Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706, United States.
Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea.
Org Lett. 2023 Jun 9;25(22):4098-4102. doi: 10.1021/acs.orglett.3c01321. Epub 2023 May 24.
Herein, we describe studies showing that Lewis acid co-catalysts can significantly broaden the scope of alkenes that can be incorporated into the photosensitized visible-light De Mayo reaction. Mechanistic studies suggest that the primary benefit of the Lewis acid is not on substrate sensitization but rather on bond-forming steps downstream of energy transfer, highlighting the diverse effects that Lewis acids can have on sensitized photoreactions.
在此，我们描述了一些研究，这些研究表明路易斯酸共催化剂可以显著拓宽可以被整合到光敏可见光 De Mayo 反应中的烯烃的范围。机理研究表明，路易斯酸的主要作用不是底物敏化，而是在能量转移后的成键步骤中，这突出了路易斯酸对敏化光反应可能产生的多种影响。
