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通过优化新型电荷传输层提高环保型钙钛矿太阳能电池的效率。

Boosting efficiency of eco-friendly perovskite solar cell through optimization of novel charge transport layers.

作者信息

Ismail Muhammad, Noman Muhammad, Tariq Jan Shayan, Imran Muhammad

机构信息

U.S.-Pakistan Center for Advanced Studies in Energy, University of Engineering and Technology, Peshawar, Pakistan.

Department of Energy Engineering Technology, University of Technology, Nowshera, Pakistan.

出版信息

R Soc Open Sci. 2023 Jun 7;10(6):230331. doi: 10.1098/rsos.230331. eCollection 2023 Jun.

DOI:10.1098/rsos.230331
PMID:37293364
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10245210/
Abstract

Formamidinium tin triiodide (FASnI) is a suitable candidate for the absorber layer in perovskite solar cells (PSC) because of its non-toxicity, narrow band gap, thermal stability and high carrier mobility. This study focuses on the analysis and improvement in the performance of FASnI-based PSCs using various inorganic charge transport materials. The copper-based materials such as CuO, CuAlO, CuSCN and CuSbS are introduced as hole transport layers due to their earth abundance, ease of manufacturing, high charge mobilities and chemical stability. Similarly, fullerene derivates (PCBM and C) are deployed as electron transport layers due to their mechanical strength, thermal conductivity and stability. The effect of these materials on optical absorption, quantum efficiency, energy band alignment, band offsets, electric field and recombination are studied in detail. The reasons for the low performance of the cell are identified and improved through design optimization. The PSC performance is analysed in both inverted and conventional architecture. Among all the structures, the best result is achieved through ITO/CuSCN/FASnI/C/Al with an efficiency of 27.26%, of 1.08 V, of 29.5 mAcm and FF of 85.6%.

摘要

三碘化甲脒锡（FASnI）因其无毒、窄带隙、热稳定性和高载流子迁移率，是钙钛矿太阳能电池（PSC）吸收层的合适候选材料。本研究聚焦于使用各种无机电荷传输材料分析和提高基于FASnI的PSC的性能。铜基材料如CuO、CuAlO、CuSCN和CuSbS由于其在地壳中的丰度、易于制造、高电荷迁移率和化学稳定性而被用作空穴传输层。同样，富勒烯衍生物（PCBM和C）由于其机械强度、热导率和稳定性而被用作电子传输层。详细研究了这些材料对光吸收、量子效率、能带排列、带隙偏移、电场和复合的影响。通过设计优化确定并改善了电池性能低下的原因。在倒置和传统结构中都对PSC性能进行了分析。在所有结构中，通过ITO/CuSCN/FASnI/C/Al获得了最佳结果，效率为27.26%，开路电压为1.08 V，短路电流密度为29.5 mA/cm²，填充因子为85.6%。

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