Zhao Xuefeng, Mao Zhongyang, Huang Xiaojun, Luo Penghui, Deng Min, Tang Mingshu
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211800, China.
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing 211800, China.
Materials (Basel). 2023 May 28;16(11):4032. doi: 10.3390/ma16114032.
Using the volume expansion generated by the hydration of the MgO expansive agent to compensate for the shrinkage deformation of concrete is considered to be an effective measure to prevent concrete shrinkage and cracking. Existing studies have mainly focused on the effect of the MgO expansive agent on the deformation of concrete under constant temperature conditions, but mass concrete in practical engineering experiences a temperature change process. Obviously, the experience obtained under constant temperature conditions makes it difficult to accurately guide the selection of the MgO expansive agent under actual engineering conditions. Based on the C50 concrete project, this paper mainly investigates the effect of curing conditions on the hydration of MgO in cement paste under actual variable temperature conditions by simulating the actual temperature change course of C50 concrete so as to provide a reference for the selection of the MgO expansive agent in engineering practice. The results show that temperature was the main factor affecting the hydration of MgO under variable temperature curing conditions, and the increase in the temperature could obviously promote the hydration of MgO in cement paste, while the change in the curing methods and cementitious system had an effect on the hydration of MgO, though this effect was not obvious.
利用氧化镁膨胀剂水化产生的体积膨胀来补偿混凝土的收缩变形,被认为是防止混凝土收缩开裂的有效措施。现有研究主要集中在恒温条件下氧化镁膨胀剂对混凝土变形的影响,但实际工程中的大体积混凝土会经历温度变化过程。显然,在恒温条件下获得的经验难以准确指导实际工程条件下氧化镁膨胀剂的选择。基于C50混凝土工程,本文通过模拟C50混凝土的实际温度变化过程,主要研究了养护条件对实际变温条件下水泥浆体中氧化镁水化的影响,以便为工程实践中氧化镁膨胀剂的选择提供参考。结果表明,温度是变温养护条件下影响氧化镁水化的主要因素,温度升高能明显促进水泥浆体中氧化镁的水化,而养护方式和胶凝体系的变化对氧化镁的水化有影响,不过这种影响不明显。