• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

硅-磷和硅-铁-磷体系的批判性评估与热力学重新优化

Critical Evaluation and Thermodynamic Re-Optimization of the Si-P and Si-Fe-P Systems.

作者信息

You Zhimin, Zhang Hao, Cui Senlin, Jiang Zhouhua, Jung In-Ho

机构信息

School of Metallurgy, Northeastern University, No. 3-11, Wenhua Road, Heping District, Shenyang 110819, China.

School of Civil Aviation, Northwestern Polytechnical University, Xi'an 710072, China.

出版信息

Materials (Basel). 2023 May 31;16(11):4099. doi: 10.3390/ma16114099.

DOI:10.3390/ma16114099
PMID:37297232
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10254834/
Abstract

Thermodynamic modeling of the Si-P and Si-Fe-P systems was performed using the CALculation of PHAse Diagram (CALPHAD) method based on critical evaluation of available experimental data in the literature. The liquid and solid solutions were described using the Modified Quasichemical Model accounting for the short-range ordering and Compound Energy Formalism considering the crystallographic structure, respectively. In the present study, the phase boundaries for the liquidus and solid Si phases of the Si-P system were reoptimized. Furthermore, the Gibbs energies of the liquid solution, (Fe)(P,Si), (Fe)(P,Si), and (Fe)(P,Si) solid solutions and FeSiP compound were carefully determined to resolve the discrepancies in previously assessed vertical sections, isothermal sections of phase diagrams, and liquid surface projection of the Si-Fe-P system. These thermodynamic data are of great necessity for a sound description of the entire Si-Fe-P system. The optimized model parameters from the present study can be used to predict any unexplored phase diagrams and thermodynamic properties within the Si-Fe-P alloys.

摘要

基于对文献中现有实验数据的严格评估，采用相图计算（CALPHAD）方法对Si-P和Si-Fe-P体系进行了热力学建模。分别使用考虑短程有序的修正准化学模型和考虑晶体结构的化合物能量形式来描述液相和固溶体。在本研究中，对Si-P体系的液相线和固态Si相的相界进行了重新优化。此外，仔细确定了液相溶液、(Fe)(P,Si)、(Fe)(P,Si)和(Fe)(P,Si)固溶体以及FeSiP化合物的吉布斯自由能，以解决先前评估的相图垂直截面、等温截面以及Si-Fe-P体系的液体表面投影中的差异。这些热力学数据对于全面描述整个Si-Fe-P体系非常必要。本研究中优化的模型参数可用于预测Si-Fe-P合金中任何未探索的相图和热力学性质。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/92fa2644d0b6/materials-16-04099-g014a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/8555473f0525/materials-16-04099-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/e0cc4f38958d/materials-16-04099-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/3933f1e671a5/materials-16-04099-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/41de86fbb55e/materials-16-04099-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/12ba17a8d103/materials-16-04099-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/8929a9549636/materials-16-04099-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/8106c0ffb3f3/materials-16-04099-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/fb283b4ff742/materials-16-04099-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/32dcf80be86b/materials-16-04099-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/e0044ca99bc8/materials-16-04099-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/d4f402526058/materials-16-04099-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/f2f0489a60c2/materials-16-04099-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/5921d0639a0c/materials-16-04099-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/92fa2644d0b6/materials-16-04099-g014a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/8555473f0525/materials-16-04099-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/e0cc4f38958d/materials-16-04099-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/3933f1e671a5/materials-16-04099-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/41de86fbb55e/materials-16-04099-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/12ba17a8d103/materials-16-04099-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/8929a9549636/materials-16-04099-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/8106c0ffb3f3/materials-16-04099-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/fb283b4ff742/materials-16-04099-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/32dcf80be86b/materials-16-04099-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/e0044ca99bc8/materials-16-04099-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/d4f402526058/materials-16-04099-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/f2f0489a60c2/materials-16-04099-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/5921d0639a0c/materials-16-04099-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a41/10254834/92fa2644d0b6/materials-16-04099-g014a.jpg

相似文献

1
Critical Evaluation and Thermodynamic Re-Optimization of the Si-P and Si-Fe-P Systems.硅-磷和硅-铁-磷体系的批判性评估与热力学重新优化
Materials (Basel). 2023 May 31;16(11):4099. doi: 10.3390/ma16114099.
2
Thermodynamic Modeling of the Au-Ge-X (X = In, Sb, Si, Zn) Ternary Systems.金-锗-X（X = 铟、锑、硅、锌）三元体系的热力学建模
Materials (Basel). 2024 May 2;17(9):2137. doi: 10.3390/ma17092137.
3
Third-Generation Thermodynamic Descriptions for Ta-Cr and Ta-V Binary Systems.Ta-Cr和Ta-V二元体系的第三代热力学描述
Materials (Basel). 2022 Mar 11;15(6):2074. doi: 10.3390/ma15062074.
4
Phase Equilibria of the In-Pd-Sn System at 500 °C and 800 °C: Experimental Study and CALPHAD Modeling.500°C和800°C下In-Pd-Sn体系的相平衡：实验研究与CALPHAD建模
Materials (Basel). 2023 Feb 17;16(4):1690. doi: 10.3390/ma16041690.
5
Phase equilibria and structural investigations in the system Al-Fe-Si.铝 - 铁 - 硅体系中的相平衡与结构研究
Intermetallics (Barking). 2011 Dec;19(12):1919-1929. doi: 10.1016/j.intermet.2011.05.003.
6
Solid-liquid equilibria for a pyrrolidinium-based common-cation ternary ionic liquid system, and for a pyridinium-based ternary reciprocal ionic liquid system: an experimental study and a thermodynamic model.基于吡咯烷鎓的普通阳离子三元离子液体体系以及基于吡啶鎓的三元互逆离子液体体系的固液平衡：实验研究与热力学模型
Phys Chem Chem Phys. 2017 Dec 20;20(1):637-657. doi: 10.1039/c7cp04678b.
7
Experimental investigation and thermodynamic modeling of phase equilibria in the Ag-Ni-Zr ternary system.Ag-Ni-Zr三元系相平衡的实验研究与热力学建模
Phys Chem Chem Phys. 2022 Sep 21;24(36):22263-22277. doi: 10.1039/d2cp03237f.
8
Phase Equilibria, Thermodynamics and Solidified Microstructure in the Copper-Zirconium-Yttrium System.铜 - 锆 - 钇体系中的相平衡、热力学与凝固微观结构
Materials (Basel). 2023 Mar 2;16(5):2063. doi: 10.3390/ma16052063.
9
Solidification Behavior of Dy-Tb-Fe Alloys through Experimental Study and Thermodynamic Calculation.通过实验研究和热力学计算研究镝-铽-铁合金的凝固行为
Materials (Basel). 2023 Jun 29;16(13):4697. doi: 10.3390/ma16134697.
10
Binary Phase Diagrams and Thermodynamic Properties of Silicon and Essential Doping Elements (Al, As, B, Bi, Ga, In, N, P, Sb and Tl).硅及主要掺杂元素（铝、砷、硼、铋、镓、铟、氮、磷、锑和铊）的二元相图及热力学性质
Materials (Basel). 2017 Jun 20;10(6):676. doi: 10.3390/ma10060676.

本文引用的文献

1
Binary Phase Diagrams and Thermodynamic Properties of Silicon and Essential Doping Elements (Al, As, B, Bi, Ga, In, N, P, Sb and Tl).硅及主要掺杂元素（铝、砷、硼、铋、镓、铟、氮、磷、锑和铊）的二元相图及热力学性质
Materials (Basel). 2017 Jun 20;10(6):676. doi: 10.3390/ma10060676.
2
Dopant and carrier concentration in Si in equilibrium with monoclinic SiP precipitates.与单斜晶系SiP沉淀处于平衡状态的硅中的掺杂剂和载流子浓度。
Phys Rev B Condens Matter. 1996 Mar 15;53(12):7836-7841. doi: 10.1103/physrevb.53.7836.