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采用无毒溶剂狭缝式涂布法制备的高性能钙钛矿太阳能电池及组件

High-Performance Perovskite Solar Cells and Modules Fabricated by Slot-Die Coating with Nontoxic Solvents.

作者信息

Li Chia-Feng, Huang Hung-Che, Huang Shih-Han, Hsiao Yu-Hung, Chaudhary Priyanka, Chang Chun-Yu, Tsai Feng-Yu, Su Wei-Fang, Huang Yu-Ching

机构信息

Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan.

Department of Materials Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan.

出版信息

Nanomaterials (Basel). 2023 May 29;13(11):1760. doi: 10.3390/nano13111760.

DOI:10.3390/nano13111760
PMID:37299663
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10254507/
Abstract

Energy shortage has become a global issue in the twenty-firt century, as energy consumption grows at an alarming rate as the fossil fuel supply exhausts. Perovskite solar cells (PSCs) are a promising photovoltaic technology that has grown quickly in recent years. Its power conversion efficiency (PCE) is comparable to that of traditional silicon-based solar cells, and scale-up costs can be substantially reduced due to its utilization of solution-processable fabrication. Nevertheless, most PSCs research uses hazardous solvents, such as dimethylformamide (DMF) and chlorobenzene (CB), which are not suitable for large-scale ambient operations and industrial production. In this study, we have successfully deposited all of the layers of PSCs, except the top metal electrode, under ambient conditions using a slot-die coating process and nontoxic solvents. The fully slot-die coated PSCs exhibited PCEs of 13.86% and 13.54% in a single device (0.09 cm) and mini-module (0.75 cm), respectively.

摘要

能源短缺已成为21世纪的全球性问题,随着化石燃料供应枯竭,能源消耗正以惊人的速度增长。钙钛矿太阳能电池(PSC)是一种很有前途的光伏技术,近年来发展迅速。其功率转换效率(PCE)与传统硅基太阳能电池相当,并且由于采用可溶液加工的制造工艺,可大幅降低扩大规模的成本。然而,大多数PSC研究使用危险溶剂,如二甲基甲酰胺(DMF)和氯苯(CB),这些溶剂不适用于大规模的环境作业和工业生产。在本研究中,我们使用狭缝式涂布工艺和无毒溶剂,在环境条件下成功沉积了除顶部金属电极外的所有PSC层。全狭缝式涂布的PSC在单个器件(0.09平方厘米)和微型模块(0.75平方厘米)中的PCE分别为13.86%和13.54%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/e8e512839538/nanomaterials-13-01760-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/8bb1ad3c7fe2/nanomaterials-13-01760-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/896ca586e937/nanomaterials-13-01760-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/3be46e32b376/nanomaterials-13-01760-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/449dd3bde63a/nanomaterials-13-01760-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/28708dcb82d0/nanomaterials-13-01760-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/1df48df8fdb6/nanomaterials-13-01760-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/e8e512839538/nanomaterials-13-01760-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/8bb1ad3c7fe2/nanomaterials-13-01760-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/896ca586e937/nanomaterials-13-01760-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/3be46e32b376/nanomaterials-13-01760-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/449dd3bde63a/nanomaterials-13-01760-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/28708dcb82d0/nanomaterials-13-01760-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/1df48df8fdb6/nanomaterials-13-01760-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef82/10254507/e8e512839538/nanomaterials-13-01760-g007.jpg

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