Rodriguez-Hornedo N
J Pharm Sci. 1986 Jun;75(6):559-61. doi: 10.1002/jps.2600750607.
It is shown that at constant supersaturation during crystallization of oxalic acid dihydrate, the growth rate equation can be solved in closed form. At low degrees of supersaturation, where nucleation is negligible, the depletion of solute from solution is described by a cube root relationship and allows for calculation of the growth rate constant.
结果表明，在二水合草酸结晶过程中，当过饱和度恒定时，生长速率方程可以用封闭形式求解。在低过饱和度下，成核可忽略不计，溶液中溶质的消耗由立方根关系描述，并可用于计算生长速率常数。
