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一种耐盐原位交联三元共聚物凝胶在大庆油田的应用。

Application of a Salt-Resistant In Situ Cross-Linked Terpolymer Gel for the Daqing Oilfield.

作者信息

Tan Xinjian, Zhang Jihong, Wang Yanan, Li Ming, Liu Jiamin, Zhu Zhengjun

机构信息

Laboratory of Enhanced Oil Recovery of Education Ministry, Northeast Petroleum University, Daqing, Heilongjiang 163318, People's Republic of China.

Exploration and Development Research Institute, CNPC Tarim Oilfield Branch, Tarim, Xinjiang 841000, People's Republic of China.

出版信息

ACS Omega. 2023 Jun 5;8(24):22223-22229. doi: 10.1021/acsomega.3c02446. eCollection 2023 Jun 20.

Abstract

Pubei Block, which is a subdivision of Daqing Oilfield, presents a challenging environment for conformance control due to its high temperature (average 80 °C) and salinity (13,451 mg/L), making it difficult for the polyacrylamide-based gel to maintain the necessary gel strength. To address this issue, this study aims to evaluate the feasibility of using a terpolymer in situ gel system that provides greater temperature and salinity resistance and pore adaptation. The terpolymer used here consists of acrylamide, acrylamido-2-methylpropane sulfonic acid, and ,'-dimethylacrylamide. We determined that a formula with a hydrolysis degree of 15.15%, a polymer concentration of 600 mg/L, and a polymer-cross-linker ratio of 2.8 yields the greatest gel strength. The hydrodynamic radius of the gel was found to be 0.39 μm, indicating no conflict with the pore and pore-throat sizes determined by the CT scan. In the core-scale evaluation, the gel treatment improved oil recovery by 19.88%, of which 9.23% was through gelant injection and 10.65% through post water injection. A pilot test began in 2019 and has continued for 36 months until now. Within this period, the oil recovery factor increased by 9.82%. The number is likely to keep going up until the water cut (so far 87.4%) reaches the economic limit.

摘要

葡北区块是大庆油田的一个细分区块,由于其高温(平均80°C)和高矿化度(13451mg/L),在实施调剖时面临着具有挑战性的环境,这使得基于聚丙烯酰胺的凝胶难以维持所需的凝胶强度。为了解决这个问题,本研究旨在评估使用一种三元共聚物原位凝胶体系的可行性,该体系具有更高的耐温、耐盐性以及更好的孔隙适应性。这里使用的三元共聚物由丙烯酰胺、2-甲基丙烯酰胺基丙烷磺酸和N,N'-二甲基丙烯酰胺组成。我们确定水解度为15.15%、聚合物浓度为600mg/L、聚合物与交联剂比例为2.8的配方能产生最大的凝胶强度。凝胶的流体力学半径为0.39μm,表明与CT扫描确定的孔隙和孔喉尺寸不存在冲突。在岩心尺度评价中,凝胶处理使采收率提高了19.88%,其中9.23%是通过注入凝胶剂实现的,10.65%是通过后续注水实现的。2019年开始了先导试验,至今已持续36个月。在此期间,采收率提高了9.82%。在含水率(目前为87.4%)达到经济极限之前,这个数字可能会持续上升。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0ced/10286091/5dee9d375128/ao3c02446_0002.jpg

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