Li Li, Chen Zhaoguang, Huang Yingzhen, Guo Zhenhao, Dong Hang, Xie Yu, Zhou Nan, Zhou Zhi
Reproductive and Genetic Hospital Citic Xiangya, Changsha, 410128 People's Republic of China.
School of Chemistry and Materials Science, Hunan Agricultural University, Changsha, 410128 People's Republic of China.
Biomass Convers Biorefin. 2023 Mar 18:1-14. doi: 10.1007/s13399-023-04006-1.
Effective in-site treatment of medical waste has become a weak link in hospitals. Pyrolysis technology is a treatment method for medical waste that can enable rapid disposal in hospital settings and relieve environmental pressure, while also producing high-value products and reducing disposal costs. In this work, the effects of feedstock ratio and temperature on product yield and components of gauze (GA) and medical bottles (MB) co-pyrolysis have been investigated. The higher yield of solid products was obtained by co-pyrolysis of GA and MB at 400 ℃. With the addition of MB and an increase in temperature for the co-pyrolysis of GA and MB in a similar ratio, the pyrolysis oil and gas yields gradually increased. According to GC-MS analysis, co-feeding 75% MB to GA improved the alcohol content from 33.21% to a maximum yield of 59.8% at a pyrolysis temperature of 700 ℃. The content of aliphatic hydrocarbon reached 38.68% when the pyrolysis temperature and MB addition ratio were 700 °C and 75%, respectively. The GC data shows that the main gas components of co-pyrolysis of GA/MB were CH and H, while the pyrolysis of pure GA or MB resulted in CO or CO. Additionally, the solid carbon products obtained have an excellent pore structure. This strategy can benefit medical waste control and resource utilization for the low-cost disposal of medical waste and the acquisition of high-value resource products.
医疗废物的有效现场处理已成为医院的一个薄弱环节。热解技术是一种医疗废物处理方法,它可以在医院环境中实现快速处置,减轻环境压力,同时还能生产高价值产品并降低处置成本。在这项工作中,研究了原料比例和温度对纱布(GA)和医疗瓶(MB)共热解产物产率和成分的影响。GA和MB在400℃下共热解获得了较高的固体产物产率。在GA和MB以相似比例共热解时,随着MB的加入和温度的升高,热解油和气的产率逐渐增加。根据气相色谱-质谱联用(GC-MS)分析,在700℃的热解温度下,向GA中加入75%的MB可使醇含量从33.21%提高到最大产率59.8%。当热解温度和MB添加比例分别为700℃和75%时,脂肪烃含量达到38.68%。GC数据表明,GA/MB共热解的主要气体成分是CH和H,而纯GA或MB的热解产生CO或CO。此外,所获得的固体碳产物具有优良的孔隙结构。该策略有利于医疗废物控制和资源利用,可实现医疗废物的低成本处置并获取高价值资源产品。