Jiang Yongcheng, Zhang Zhenming, Zhang Jiachun
College of Resources and Environment Engineering, Guizhou University, Guiyang 550025, China.
Guizhou Institute of Biology, Guizhou Academic of Science, Guiyang 550009, China.
Toxics. 2023 Jun 2;11(6):502. doi: 10.3390/toxics11060502.
This study investigated the relationship between the characteristics of quality components and trace elements of Niaowang tea from Guizhou Province in mountainous plateau areas. The contents of catechin monomers and eight other trace elements were measured using high-performance liquid chromatography (HPLC) and inductively coupled plasma mass spectrometry (ICP-MS), respectively. The results showed that the tender summer leaves of Niaowang tea in Guizhou Province had the highest content of catechins at 3558.152226.52 μg·g. The content of ester catechins was the highest in summer, amounting to 69.7572.42% of the total catechins. The content of non-ester catechins was the highest in autumn, reaching 52.54~62.28% of the total catechins; among ester catechins, the mass fraction of epigallocatechin gallate (EGCG) showed a pattern of mature summer leaves > tender summer leaves > mature autumn leaves > tender autumn leaves, and the mass fractions of gallocatechin gallate (GCG) and epicatechin gallate (ECG) were larger in autumn than in summer; gallocatechin (GC) had no significant correlation with different trace elements, and Mn had no significant correlations with different catechin monomers. EGCG was significantly negatively correlated with As, Se, Hg, Pb, Ni, and Zn. Additionally, gallic acid (GA) was significantly negatively correlated with As, Hg and Ni. Other catechin monomers were largely significantly positively correlated with trace elements. The biochemical indicators of the phenotype of Niaowang tea show that the summer and autumn buds are suited for making high-quality green tea.
本研究调查了高原山区贵州省鸟王茶品质成分特征与微量元素之间的关系。分别采用高效液相色谱法(HPLC)和电感耦合等离子体质谱法(ICP-MS)测定儿茶素单体及其他8种微量元素的含量。结果表明,贵州省鸟王茶的夏季嫩梢儿茶素含量最高,为3558.152226.52μg·g。酯型儿茶素含量在夏季最高,占儿茶素总量的69.7572.42%。非酯型儿茶素含量在秋季最高,占儿茶素总量的52.54~62.28%;在酯型儿茶素中,表没食子儿茶素没食子酸酯(EGCG)的质量分数呈现成熟夏叶>嫩夏叶>成熟秋叶>嫩秋叶的规律,而没食子儿茶素没食子酸酯(GCG)和表儿茶素没食子酸酯(ECG)的质量分数秋季高于夏季;儿茶素(GC)与不同微量元素无显著相关性,锰与不同儿茶素单体无显著相关性。EGCG与砷、硒、汞、铅、镍和锌显著负相关。此外,没食子酸(GA)与砷、汞和镍显著负相关。其他儿茶素单体与微量元素大多显著正相关。鸟王茶表型的生化指标表明,夏芽和秋芽适合制作高品质绿茶。