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手性电致发光的薄膜钙钛矿介电空穴。

Chiral electroluminescence from thin-film perovskite metacavities.

机构信息

Department of Materials Science and Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea.

School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea.

出版信息

Sci Adv. 2023 Jun 28;9(26):eadh0414. doi: 10.1126/sciadv.adh0414.

Abstract

Chiral light sources realized in ultracompact device platforms are highly desirable for various applications. Among active media used for thin-film emission devices, lead-halide perovskites have been extensively studied for photoluminescence due to their exceptional properties. However, up to date, there have been no demonstrations of chiral electroluminescence with a substantial degree of circular polarization (DCP) based on perovskite materials, being critical for the development of practical devices. Here, we propose a concept of chiral light sources based on a thin-film perovskite metacavity and experimentally demonstrate chiral electroluminescence with a peak DCP approaching 0.38. We design a metacavity created by a metal and a dielectric metasurface supporting photonic eigenstates with a close-to-maximum chiral response. Chiral cavity modes facilitate asymmetric electroluminescence of pairs of left and right circularly polarized waves propagating in the opposite oblique directions. The proposed ultracompact light sources are especially advantageous for many applications requiring chiral light beams of both helicities.

摘要

超紧凑器件平台中实现的手性光源在各种应用中是非常需要的。在用于薄膜发射器件的主动介质中,由于其特殊的性质,卤化铅钙钛矿已被广泛研究用于光致发光。然而,到目前为止,还没有基于钙钛矿材料的具有相当大圆偏振度(DCP)的手性电致发光的演示,这对于实际器件的发展是至关重要的。在这里,我们提出了一种基于薄膜钙钛矿介腔的手性光源的概念,并实验证明了峰值 DCP 接近 0.38 的手性电致发光。我们设计了一个由金属和介电超表面构成的介腔,该介腔支持具有接近最大手性响应的光子本征态。手性腔模促进了在相反斜向传播的一对左旋和右旋圆偏振波的不对称电致发光。所提出的超紧凑光源对于许多需要两种手性光束的应用特别有利。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e3d/10306290/7b31c53d4b55/sciadv.adh0414-f1.jpg

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