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碳纤维增强PA11/PLA复合材料在X波段频率范围内的电磁干扰屏蔽性能

Electromagnetic Interference Shielding Performances of Carbon-Fiber-Reinforced PA11/PLA Composites in the X-Band Frequency Range.

作者信息

Ucpinar Durmaz Bedriye, Salman Alp Oral, Aytac Ayse

机构信息

Department of Chemical Engineering, Engineering Faculty, Kocaeli University, Kocaeli 41380, Türkiye.

Department of Electronics and Communication Engineering, Engineering Faculty, Kocaeli University, Kocaeli 41001, Türkiye.

出版信息

ACS Omega. 2023 Jun 15;8(25):22762-22773. doi: 10.1021/acsomega.3c01656. eCollection 2023 Jun 27.

Abstract

To solve the problem of increasing electromagnetic pollution, it is crucial to develop electromagnetic interference (EMI) shielding materials. Using lightweight, inexpensive polymeric composites instead of currently used metal shielding materials is promising. Therefore, bio-based polyamide 11/poly(lactic acid) composites with various carbon fiber (CF) amounts were prepared using commercial extrusion and injection/compression molding methods. The prepared composites' morphological, thermal, electrical conductivity, dielectric, and EMI shielding characteristics were investigated. The strong adhesion between the matrix and CF is confirmed by scanning electron microscopy. The addition of CF led to an increase in thermal stability. As CFs formed a conductive network in the matrix, direct current (DC) and alternative current (AC) conductivities of the matrix increased. Dielectric spectroscopy measurements showed an increase in the dielectric permittivity/energy-storage capability of the composites. Thus, the EMI shielding effectiveness (EMI SE) has also increased with the inclusion of CF. The EMI SE of the matrix increased to 15, 23, and 28 dB, respectively, with the addition of 10-20-30 wt % CF at 10 GHz, and these values are comparable or higher than other CF-reinforced polymer composites. Further analysis revealed that shielding was primarily accomplished by the reflection mechanism similar to the literature data. As a result, an EMI shielding material has been developed that can be used in commercially practical applications in the X-band region.

摘要

为了解决日益严重的电磁污染问题,开发电磁干扰(EMI)屏蔽材料至关重要。使用轻质、廉价的聚合物复合材料替代目前使用的金属屏蔽材料具有广阔前景。因此,采用商业挤出和注射/压缩成型方法制备了具有不同碳纤维(CF)含量的生物基聚酰胺11/聚乳酸复合材料。对制备的复合材料的形态、热性能、电导率、介电性能和EMI屏蔽特性进行了研究。通过扫描电子显微镜证实了基体与CF之间的强附着力。CF的加入导致热稳定性提高。由于CF在基体中形成了导电网络,基体的直流电(DC)和交流电(AC)导率增加。介电谱测量表明复合材料的介电常数/储能能力增加。因此,随着CF的加入,EMI屏蔽效能(EMI SE)也有所提高。在10 GHz频率下,随着10-20-30 wt% CF的加入,基体的EMI SE分别提高到15、23和28 dB,这些值与其他CF增强聚合物复合材料相当或更高。进一步分析表明,屏蔽主要通过类似于文献数据的反射机制实现。结果,开发出了一种可用于X波段区域商业实际应用的EMI屏蔽材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f59c/10308563/ca0d5b3e0d6f/ao3c01656_0002.jpg

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