Wang Zelinlan, Zhao Zehui, Wen Gang, Zhu Yantong, Chen Jichen, Jing Xueshan, Sun Shize, Zhang Liwen, Liu Xiaolin, Chen Huawei
Institute of Bionic Micro-Nano Systems, School of Mechanical Engineering and Automation, Beihang University, Beijing 100191, China.
State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, People's Republic of China.
ACS Nano. 2023 Jul 25;17(14):13724-13733. doi: 10.1021/acsnano.3c03023. Epub 2023 Jul 5.
Ice accumulation on surfaces significantly jeopardizes the operational security and economic effectiveness of equipment. As one of the efficient anti-icing strategies, fracture-induced ice detachment strategy can realize low ice adhesion strength and is feasible for large-area anti-icing, but its application in harsh environment is restrained by mechanical robustness deterioration due to ultralow elastic moduli. It is still a challenge for fracture-promoted interfaces to reach ultralow ice adhesion and maintain strong mechanical robustness. Drawing inspiration from subcutaneous tissue, we propose a multiscale interpenetrating reinforcing method to develop a fracture-promoted ultraslippery ice detachment interface. Our approach minimizes elastic deformation and the stress threshold of fracture initiation during ice detachment, ensuring fast and noninjurious ice detachment on the interface. At the same time, this method reinforces the mechanical robustness of the fracture-promoted ultraslippery interface, making it possible to ensure long-term operation under harsh conditions. The superiority is revealed by ultralow ice adhesion strength below 20 kPa at -30 °C even after 200 continuous abrasion cycles, as well as efficient ice shedding during dynamic anti-icing tests, which is clarified by theoretical prediction and experimental verification. This work is expected to enlighten the design of next-generation durable anti-icing interface.
表面结冰会严重危及设备的运行安全和经济效益。作为一种高效的防冰策略,断裂诱导冰脱落策略能够实现较低的冰附着力,适用于大面积防冰,但由于超低弹性模量导致机械强度下降,其在恶劣环境中的应用受到限制。对于促进断裂的界面而言,实现超低冰附着力并保持强大的机械强度仍是一项挑战。受皮下组织启发,我们提出一种多尺度互穿增强方法,以开发促进断裂的超滑冰脱落界面。我们的方法可将冰脱落过程中的弹性变形和断裂起始应力阈值降至最低,确保界面上的冰快速且无损地脱落。同时,该方法增强了促进断裂的超滑界面的机械强度,使其能够在恶劣条件下长期运行。即使经过200次连续磨损循环,在-30°C时冰附着力强度仍低于20 kPa,动态防冰测试中的高效冰脱落揭示了该方法的优越性,这通过理论预测和实验验证得到了阐明。这项工作有望为下一代耐用防冰界面的设计提供启示。