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高温处理后纤维增强二氧化硅气凝胶隔热性能的演变

The Evolution of Insulation Performance of Fiber-Reinforced Silica Aerogel after High-Temperature Treatment.

作者信息

Gao Rui, Zhou Zhangjian, Zhang Hongbo, Zhang Xiaoge, Wu Yuming

机构信息

School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China.

Zhongfa Innovation (Beijing) Energy Conservation Technology Co., Ltd., Beijing 100086, China.

出版信息

Materials (Basel). 2023 Jul 7;16(13):4888. doi: 10.3390/ma16134888.

Abstract

Fiber-reinforced silica aerogel blankets (FRABs) are an important high-temperature thermal insulation material for industry applications that have emerged in recent years. In order to better understand the performance evolution of FRABs at high temperatures, the effect of heat treatment at different temperatures on the performance of FRABs as well as their base material, hydrophobic silica aerogel powder and glass wool, was investigated. The property evolution of the hydrophobic silica aerogel powder showed two stages with an increase in thermal treatment temperatures. The skeleton structure of the aerogel remained unchanged, but the residual organic chemicals, such as hydrophobic groups, were decomposed when the heat treatment temperature was lower than 400 °C. Above 400 °C, the skeleton began to shrink with the increase in temperature, which led to an increase in thermal conductivity. The structure and room-temperature thermal conductivity of the glass wool blanket were less affected by a heat treatment temperature under 600 °C. Therefore, the performance degradation of FRABs at high temperatures is mainly due to the change in the aerogel powder. The insulation performance of the glass wool and FRAB at high temperatures was studied using a heating table which was designed to simulate working conditions. The energy savings of using FRABs instead of glass fiber were calculated and are discussed here.

摘要

纤维增强二氧化硅气凝胶毡(FRABs)是近年来出现的一种重要的工业应用高温隔热材料。为了更好地了解FRABs在高温下的性能演变,研究了不同温度热处理对FRABs及其基础材料疏水二氧化硅气凝胶粉末和玻璃棉性能的影响。随着热处理温度的升高,疏水二氧化硅气凝胶粉末的性能演变呈现两个阶段。当热处理温度低于400℃时,气凝胶的骨架结构保持不变,但残余有机化学物质(如疏水基团)会分解。高于400℃时,骨架开始随着温度升高而收缩,导致热导率增加。600℃以下的热处理温度对玻璃棉毡的结构和室温热导率影响较小。因此,FRABs在高温下的性能退化主要是由于气凝胶粉末的变化。使用加热台模拟工作条件,研究了玻璃棉和FRAB在高温下的隔热性能。计算并讨论了使用FRABs代替玻璃纤维的节能情况。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b50/10343770/4d4fc750dbc9/materials-16-04888-g001.jpg

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