Baivier Clara, Hammami Imen, Benzerga Ratiba, Graça Manuel P F, Costa Luís C
CNRS, IETR-UMR 6164, University of Rennes, 35000 Rennes, France.
I3N and Department of Physics, University of Aveiro, 3810-193 Aveiro, Portugal.
Nanomaterials (Basel). 2023 Jun 27;13(13):1955. doi: 10.3390/nano13131955.
This work investigates the dielectric properties of barium titanate/gadolinium ferrite ceramic composites, with different concentrations of each material. Our objective was to increase the storage ability of this material, finding a compromise between high permittivity and low dielectric losses. A two-step sintering procedure was used in the preparation of the composites to attain the desired results. Their morphological, structural and electrical properties were tested using scanning electron microscopy, X-Ray powder diffraction and impedance spectroscopy, respectively. Dielectric characterizations were performed on the frequency band of 100 Hz-1 MHz and for different temperatures (180-380 K). The best compromise between barium titanate and gadolinium ferrite in the composition was calculated in order to obtain a potential material for electrical energy storage. The sample with 25% gadolinium ferrite presented the best results. The dielectric constant reached values of the order of 2000, at 1 kHz and 340 K. It was also important not to have very high losses, and this was confirmed by the calculated loss tangent.
这项工作研究了不同材料浓度的钛酸钡/钆铁氧体陶瓷复合材料的介电性能。我们的目标是提高这种材料的储能能力,在高介电常数和低介电损耗之间找到平衡。在复合材料的制备过程中采用了两步烧结程序以达到预期效果。分别使用扫描电子显微镜、X射线粉末衍射和阻抗谱对其形态、结构和电学性能进行了测试。在100 Hz - 1 MHz频段以及不同温度(180 - 380 K)下进行了介电特性表征。为了获得一种潜在的电能存储材料,计算了钛酸钡和钆铁氧体在成分中的最佳配比。含有25%钆铁氧体的样品表现出最佳结果。在1 kHz和340 K时,介电常数达到了2000左右。同样重要的是不能有非常高的损耗,这一点通过计算得到的损耗角正切得到了证实。