Poly(arylene ether nitrile) Based Dielectrics with High Energy Storage Properties: A Review.

Polymer-based nanocomposites have demonstrated significant strategic value in dielectric energy storage systems due to their tunable high energy density and rapid charge-discharge efficiency. Poly(arylene ether nitrile) (PEN), owing to its superior thermal stability, high mechanical strength, chemical corrosion resistance, and outstanding dielectric properties, exhibits distinct advantages in the field of high-performance dielectric energy storage devices. This review focuses on key strategies for enhancing the dielectric energy storage performance of PEN-based composites, emphasizing molecular engineering approaches, microstructural design, the multiscale interface regulation mechanisms within composite systems, and the optimization of the dielectric constant () and breakdown strength () through thermal stretching. Furthermore, the potential of PEN-based polymer composites in energy storage devices is highlighted, and future research directions are proposed, including the establishment of a dynamic balance mechanism between dielectric/insulating properties and the development of novel composite systems that offer both high energy storage density and stability. These advancements will provide the material foundation for the miniaturization and intellectualization of advanced pulse power equipment.