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基于库拉索芦荟的石墨烯偶联酚藏花红光催化剂,通过模拟自然光合作用途径来生成和再生氨和 NADH。

Aloe vera-derived graphene-coupled phenosafranin photocatalyst for generation and regeneration of ammonia and NADH by mimicking natural photosynthetic route.

机构信息

Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, Uttar Pradesh, India.

Department of Chemical Engineering, Madan Mohan Malaviya University of Technology, Gorakhpur, Uttar Pradesh, India.

出版信息

Photochem Photobiol. 2024 Jan-Feb;100(1):41-51. doi: 10.1111/php.13831. Epub 2023 Jul 17.

Abstract

Aloe vera-derived graphene (ADG) coupled system photocatalyst, mimicking natural photosynthesis, is one of the most promising ways for converting solar energy into ammonia (NH ) and nicotinamide adenine dinucleotide (NADH) that have been widely used to make the numerous chemicals such as fertilizer and fuel. In this study, we report the synthesis of the aloe vera-derived graphene-coupled phenosafranin (ADGCP) acting as a highly efficient photocatalyst for the generation of NH and regeneration of NADH from nitrogen (N ) and oxidized form of nicotinamide adenine dinucleotide (NAD ). The results show a benchmark instance for mimicking natural photosynthesis activity as well as the practical applications for the solar-driven selective formation of NH and the regeneration of NADH by using the newly designed photocatalyst.

摘要

基于库拉索芦荟衍生的石墨烯(ADG)耦合体系的光催化剂,模拟了自然光合作用,是将太阳能转化为氨(NH )和烟酰胺腺嘌呤二核苷酸(NADH)的最有前途的方法之一,这些物质被广泛用于制造化肥和燃料等多种化学物质。在这项研究中,我们报告了基于库拉索芦荟衍生的石墨烯耦合酚藏花红(ADGCP)的合成,它作为一种高效的光催化剂,可将氮气(N )和氧化型烟酰胺腺嘌呤二核苷酸(NAD )转化为氨(NH )和烟酰胺腺嘌呤二核苷酸(NADH)。结果表明,该光催化剂为模拟自然光合作用活性以及利用新型光催化剂实现太阳能驱动的氨选择性合成和 NADH 再生的实际应用提供了一个基准实例。

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