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将手术口罩升级为用于超级电容器技术的碳基薄膜电极。

Upcycling of surgical facemasks into carbon based thin film electrode for supercapacitor technology.

机构信息

Department of Physics, University of Jammu, Jammu, Jammu and Kashmir, 180006, India.

Centre for Nano-Biosensors, Department of Prosthodontics, Saveetha Dental College and Hospitals, Saveetha Institute of Medical and Technical Sciences, Chennai, Tamil Nadu, 600077, India.

出版信息

Sci Rep. 2023 Jul 27;13(1):12146. doi: 10.1038/s41598-023-37499-x.

Abstract

Polypropylene (PP), a commonly used plastic, is used for making the outer layers of a surgical face mask. In 2020, around 3 billion surgical face masks were disposed into the environment, causing a huge threat to wildlife, aquatic life, and ecosystems. In this work, we have reported the sulfonation technique for stabilizing the surgical face masks and their conversion into carbon nanoparticles for application as a supercapacitor electrode. The electrode is fabricated by preparing a slurry paste of carbon nanoparticles and pasting it on a conductive wearable fabric. To investigate the performance of the carbon thin film electrode, electrochemical techniques are employed. The Cyclic Voltammetry (CV) analysis performed at different scan rates in a 6 molar KOH electrolyte reveals that the carbon thin film acts as a positive electrode. At 4 A g, the electrode shows a specific capacitance of 366.22 F g and 100% retention of specific capacitance for 8000 cycles. A two-electrode asymmetric device is fabricated using carbon thin film as the positive electrode, NiO thin film as the negative electrode, and a KOH separator between two electrodes. The device shows a specific capacitance of 113.73 F g at 1.3 A g and glows a red LED for 6 min. This work is a step towards upcycling the waste produced from surgical face masks used during the COVID-19 pandemic and its application for energy storage.

摘要

聚丙烯(PP)是一种常用的塑料,用于制造外科口罩的外层。2020 年,大约有 30 亿个外科口罩被丢弃到环境中,对野生动物、水生生物和生态系统造成了巨大威胁。在这项工作中,我们报告了一种用于稳定外科口罩并将其转化为碳纳米颗粒用作超级电容器电极的磺化技术。该电极是通过制备碳纳米颗粒的浆料糊并将其粘贴在导电可穿戴织物上来制造的。为了研究碳薄膜电极的性能,采用电化学技术进行了研究。在 6 摩尔 KOH 电解质中以不同的扫描速率进行的循环伏安法(CV)分析表明,碳薄膜作为正极起作用。在 4 A g 下,电极显示出 366.22 F g 的比电容和 8000 次循环 100%的比电容保持率。使用碳薄膜作为正极、NiO 薄膜作为负极以及两个电极之间的 KOH 分离器制造了一个两电极不对称器件。该器件在 1.3 A g 下显示出 113.73 F g 的比电容,并为红色 LED 供电 6 分钟。这项工作是朝着利用 COVID-19 大流行期间使用的外科口罩产生的废物进行升级改造并将其应用于储能迈出的一步。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/964e/10374911/980869a3c477/41598_2023_37499_Fig1_HTML.jpg

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