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铈和镧作为副产品如何促进稀土稳定生产及新型合金的发展。

How Cerium and Lanthanum as Coproducts Promote Stable Rare Earth Production and New Alloys.

作者信息

Sims Zachary C, Kesler Michael S, Henderson Hunter B, Castillo Emilio, Fishman Tomer, Weiss David, Singleton Prentice, Eggert Roderick, McCall Scott K, Rios Orlando

机构信息

Lawrence Livermore National Laboratory, Livermore, CA USA.

Critical Materials Institute, Ames, IA USA.

出版信息

J Sustain Metall. 2022;8(3):1225-1234. doi: 10.1007/s40831-022-00562-4. Epub 2022 Jul 5.

Abstract

The largest outputs of rare earth mining are the low-value byproducts cerium and lanthanum, which burden rare earth supply chains because they must be separated from more desirable rare earths used in magnet production. Promoting demand for cerium and lanthanum can potentially diversify the economics of rare earth mining and improve supply chain stability for all rare earth elements. A promising avenue for increasing byproduct rare earth element demand is their use in aluminum alloys; an application for cerium and lanthanum offering multiple benefits to manufacturing such as energy reduction and improved throughput. Experimental materials science and economic implications of Al-rare earth element alloys will be discussed. We show that Al-La/Ce alloys have elevated mechanical strength compared to more traditional aluminum alloys, in some formulations can be used without heat treatment, and possess a highly castable eutectic microstructure. This report presents the use of cerium and lanthanum in aluminum alloys as an example of how supply chain focused approaches to technological development can benefit stakeholders at every step in production.

摘要

稀土开采的最大产出物是低价值副产品铈和镧,这给稀土供应链带来了负担,因为它们必须与用于磁体生产的更具价值的稀土元素分离。促进对铈和镧的需求有可能使稀土开采的经济模式多样化,并提高所有稀土元素的供应链稳定性。增加稀土副产品需求的一个有前景的途径是将它们用于铝合金;铈和镧的这种应用为制造业带来了多种好处,如降低能耗和提高产量。将讨论铝-稀土元素合金的实验材料科学及其经济影响。我们表明,与更传统的铝合金相比,铝-镧/铈合金具有更高的机械强度,在某些配方中无需热处理即可使用,并且具有高度可铸造的共晶微观结构。本报告以铈和镧在铝合金中的应用为例,说明以供应链为重点的技术开发方法如何能使生产各环节的利益相关者受益。

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本文引用的文献

1
Uncovering the end uses of the rare earth elements.揭示稀土元素的最终用途。
Sci Total Environ. 2013 Sep 1;461-462:781-4. doi: 10.1016/j.scitotenv.2013.02.099. Epub 2013 Apr 18.

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