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CuO@FeONC 增强的光催化活性和抗病毒评估用于阿莫西林降解和 SARS-CoV-2 治疗。

Enhanced photocatalytic activity and antiviral evaluation of CuO@FeONC for amoxicillin degradation and SARS-CoV-2 treatment.

机构信息

Laboratory of Biotechnology Biomaterial and Condensed Matter, Faculty of Technology, University of El Oued, 39000 El-Oued, Algeria.

Department of Process Engineering, Faculty of Technology, University of El Oued, 39000 El-Oued, Algeria.

出版信息

Nanotechnology. 2023 Aug 16;34(44). doi: 10.1088/1361-6528/acebfa.

Abstract

Copper oxide nanoparticles (CuO NPs) and CuO NPs decorated with hematite (FeO) nanocomposites (CuO@FeONC) were biosynthesized by a green method usingleaves extract. The NC were characterized using various techniques, including x-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive x-ray spectroscopy, and UV-vis spectroscopy. The results showed that the synthesized CuO and CuO@FeONC were crystalline with a monoclinic crystal structure and contained functional groups responsible for catalytic activity. The size of the nanocomposites ranged from 39.5 to 45.9 nm, and they exhibited a variety of agglomerated or aggregated shapes. The CuO@FeONC showed improved photocatalytic activity for the degradation of antibiotics in water and wastewater and promising antiviral activity against SARS-CoV-2, indicating its potential for use in disinfection applications. The study investigated the impact of irradiation time on the photocatalytic degradation of Amoxicillin and found that increasing the irradiation time led to a higher degradation rate. The band gap energy () for pure CuO NPs was around 2.4 eV and dropped to 1.6 eV with CuO@FeONC. In summary, the CuO@FeONC has the potential to be an efficient photocatalyst and promising antiviral agent for environmental remediation. The CuO@FeOnanocomposites have been found to possess a high degree of efficacy in inactivating SARS-CoV-2 infectivity. The results of the study indicate that the nanocomposites exhibit potent anti-viral properties and hold significant potential for use in mitigating the spread of the virus.

摘要

氧化铜纳米粒子 (CuO NPs) 和氧化铁纳米粒子修饰的氧化铜纳米复合材料 (CuO@FeONC) 采用绿色方法,使用叶片提取物合成。使用各种技术对 NC 进行了表征,包括 X 射线衍射、傅里叶变换红外光谱、扫描电子显微镜、能谱和紫外可见光谱。结果表明,合成的 CuO 和 CuO@FeONC 是结晶的,具有单斜晶结构,并含有负责催化活性的官能团。纳米复合材料的尺寸范围为 39.5 至 45.9nm,它们表现出各种团聚或聚集的形状。CuO@FeONC 表现出对水中和废水中抗生素的光催化降解活性的提高,以及对 SARS-CoV-2 的抗病毒活性,表明其在消毒应用中的潜力。该研究考察了辐照时间对阿莫西林光催化降解的影响,发现辐照时间的增加导致降解率的提高。纯 CuO NPs 的带隙能 () 约为 2.4eV,而 CuO@FeONC 则降至 1.6eV。总之,CuO@FeONC 具有作为高效光催化剂和有前途的抗病毒剂用于环境修复的潜力。CuO@FeOnanocomposites 已被发现具有高度的 SARS-CoV-2 感染力失活效果。研究结果表明,该纳米复合材料具有很强的抗病毒特性,在减轻病毒传播方面具有很大的潜力。

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