Center for Interdisciplinary Research in Health (CIIS), Faculty of Dental Medicine (FMD), Universidade Católica Portuguesa (UCP), 3504-505, Viseu, Portugal.
University Institute of Health Sciences (IUCS), CESPU, 4585-116, Gandra PRD, Portugal.
Clin Oral Investig. 2023 Sep;27(9):5679-5693. doi: 10.1007/s00784-023-05189-7. Epub 2023 Aug 18.
The aim of this in vitro study was to evaluate the light transmission through five different resin-matrix composites regarding the inorganic filler content.
Resin-matrix composite disc-shaped specimens were prepared on glass molds. Three traditional resin-matrix composites contained inorganic fillers at 74, 80, and 89 wt. % while two flowable composites revealed 60 and 62.5 wt. % inorganic fillers. Light transmission through the resin-matrix composites was assessed using a spectrophotometer with an integrated monochromator before and after light curing for 10, 20, or 40s. Elastic modulus and nanohardness were evaluated through nanoindentation's tests, while Vicker's hardness was measured by micro-hardness assessment. Chemical analyses were performed by FTIR and EDS, while microstructural analysis was conducted by optical microscopy and scanning electron microscopy. Data were evaluated using two-way ANOVA and Tukey's test (p < 0.05).
After polymerization, optical transmittance increased for all specimens above 650-nm wavelength irradiation since higher light exposure time leads to increased light transmittance. At 20- or 40-s irradiation, similar light transmittance was recorded for resin composites with 60, 62, 74, or 78-80 wt. % inorganic fillers. The lowest light transmittance was recorded for a resin-matrix composite reinforced with 89 wt. % inorganic fillers. Thus, the size of inorganic fillers ranged from nano- up to micro-scale dimensions and the high content of micro-scale inorganic particles can change the light pathway and decrease the light transmittance through the materials. At 850-nm wavelength, the average ratio between polymerized and non-polymerized specimens increased by 1.6 times for the resin composite with 89 wt. % fillers, while the composites with 60 wt. % fillers revealed an increased ratio by 3.5 times higher than that recorded at 600-nm wavelength. High mean values of elastic modulus, nano-hardness, and micro-hardness were recorded for the resin-matrix composites with the highest inorganic content.
A high content of inorganic fillers at 89 wt.% decreased the light transmission through resin-matrix composites. However, certain types of fillers do not interfere on the light transmission, maintaining an optimal polymerization and the physical properties of the resin-matrix composites.
The type and content of inorganic fillers in the chemical composition of resin-matrix composites do affect their polymerization mode. As a consequence, the clinical performance of resin-matrix composites can be compromised, leading to variable physical properties and degradation.
本体外研究旨在评估五种不同树脂基质复合材料的透光率与其无机填料含量的关系。
将树脂基质复合材料的圆盘状样本制备在玻璃模具上。三种传统的树脂基质复合材料含有 74、80 和 89wt%的无机填料,而两种流动性复合材料则含有 60 和 62.5wt%的无机填料。使用分光光度计和集成单色仪在光固化前和光固化 10、20 或 40s 后评估树脂基质复合材料的透光率。通过纳米压痕试验评估弹性模量和纳米硬度,通过显微硬度评估测量维氏硬度。通过傅里叶变换红外光谱(FTIR)和能谱(EDS)进行化学分析,通过光学显微镜和扫描电子显微镜进行微观结构分析。使用双因素方差分析和 Tukey 检验(p<0.05)进行数据评估。
聚合后,所有在 650nm 以上波长的试件的光透过率都增加了,因为更高的光暴露时间会导致光透过率增加。在 20 或 40s 的照射下,具有 60、62、74 或 78-80wt%无机填料的树脂复合材料记录到相似的光透过率。光透过率最低的是用 89wt%无机填料增强的树脂基质复合材料。因此,无机填料的尺寸范围从纳米到微米级,而高含量的微米级无机颗粒可以改变光路径并降低材料的光透过率。在 850nm 波长下,具有 89wt%填料的树脂复合材料的聚合和未聚合试件之间的平均比值增加了 1.6 倍,而具有 60wt%填料的复合材料的比值增加了 3.5 倍,高于在 600nm 波长下记录的值。具有最高无机含量的树脂基质复合材料记录到高的弹性模量、纳米硬度和显微硬度平均值。
89wt%高含量的无机填料会降低树脂基质复合材料的透光率。然而,某些类型的填料不会干扰光的传输,从而保持树脂基质复合材料的最佳聚合和物理性能。
树脂基质复合材料化学成分中的无机填料的类型和含量会影响其聚合方式。因此,树脂基质复合材料的临床性能可能会受到影响,导致物理性能发生变化和降解。