(1-咪唑-κ)[-(2-氧化苄叉基)酪氨酸根-κ,,']铜(II)的晶体结构和 Hirshfeld 表面分析
Crystal structure and Hirshfeld surface analysis of (1-imidazole-κ)[-(2-oxido-benzyl-idene)tyrosinato-κ,,']copper(II).
作者信息
Suzuki Soma, Akiyama Yukihito, Nakane Daisuke, Akitsu Takashiro
机构信息
Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.
出版信息
Acta Crystallogr E Crystallogr Commun. 2023 Jun 2;79(Pt 7):596-599. doi: 10.1107/S2056989023004735. eCollection 2023 Jun 1.
The title copper(II) complex, [Cu(CHNO)(CHN)], consists of a tridentate ligand synthesized from l-tyrosine and salicyl-aldehyde. One imidazole mol-ecule is additionally coordinating to the copper(II) ion. The crystal structure features N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are from H⋯H (37.9%), C⋯H (28.2%) and O⋯H/H⋯O (21.2%) contacts.
标题为铜（II）配合物[Cu(CHNO)(CHN)]，由l-酪氨酸和水杨醛合成的三齿配体组成。另外还有一个咪唑分子与铜（II）离子配位。晶体结构具有N-H⋯O、O-H⋯O和C-H⋯O氢键。 Hirshfeld表面分析表明，对堆积起最重要作用的是H⋯H（37.9%）、C⋯H（28.2%）和O⋯H/H⋯O（21.2%）接触。
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