Bobrowski Artur, Woźniak Faustyna, Żymankowska-Kumon Sylwia, Kaczmarska Karolina, Grabowska Beata, Dereń Michał, Żuchliński Robert
Faculty of Foundry Engineering, AGH University of Krakow, Reymonta 23 Str., 30-059 Kraków, Poland.
Bydgoszcz Cast Iron Foundry, Zygmunta Augusta 11 Str., 85-082 Bydgoszcz, Poland.
Materials (Basel). 2023 Aug 8;16(16):5507. doi: 10.3390/ma16165507.
This article presents the findings of a study focusing on the gas generation of 3D-printed cores fabricated using binder-jetting technology with furfuryl resin. The research aimed to compare gas emission levels, where the volume generated during the thermal degradation of the binder significantly impacts the propensity for gaseous defects in foundries. The study also investigated the influence of the binder type (conventional vs. 3D-printed dedicated binder) and core construction (shell core) on the quantity of gaseous products from the BTEX group formed during the pouring of liquid foundry metal into the cores. The results revealed that the emitted gas volume during the thermal decomposition of the organic binder depended on the core sand components and binder type. Cores produced using conventional methods emitted the least gases due to lower binder content. Increasing Kaltharz U404 resin to 1.5 parts by weight resulted in a 37% rise in gas volume and 27% higher benzene emission. Adopting shell cores reduced gas volume by over 20% (retaining sand with hardener) and 30% (removing sand with hardener), presenting an eco-friendly solution with reduced benzene emissions and core production costs. Shell cores facilitated the quicker removal of gaseous binder decomposition products, reducing the likelihood of casting defects. The disparity in benzene emissions between 3D-printed and vibratory-mixed solid cores is attributed to the sample preparation process, wherein 3D printing ensured greater uniformity.
本文介绍了一项研究的结果,该研究聚焦于使用糠醇树脂通过粘结剂喷射技术制造的3D打印型芯的气体生成情况。该研究旨在比较气体排放水平,因为粘结剂热降解过程中产生的气体体积对铸造厂中产生气态缺陷的倾向有重大影响。该研究还调查了粘结剂类型(传统粘结剂与3D打印专用粘结剂)和型芯结构(壳型芯)对液态铸造金属浇注到型芯过程中形成的BTEX组气态产物数量的影响。结果表明,有机粘结剂热分解过程中排放的气体体积取决于型芯砂成分和粘结剂类型。由于粘结剂含量较低,采用传统方法生产的型芯排放的气体最少。将卡尔萨尔兹U404树脂增加到1.5重量份会导致气体体积增加37%,苯排放量增加27%。采用壳型芯可使气体体积减少20%以上(保留含固化剂的砂)和30%(去除含固化剂的砂),这是一种环保解决方案,可减少苯排放和型芯生产成本。壳型芯有助于更快地去除气态粘结剂分解产物,降低铸造缺陷的可能性。3D打印实心型芯和振动混合实心型芯之间苯排放量的差异归因于样品制备过程,其中3D打印确保了更高的均匀性。