Xie Yun, Wu Xinyue, Shi Yuxin, Peng Yi, Zhou Huijie, Wu Xiaohui, Ma Jiao, Jin Jiangchen, Pi Yecan, Pang Huan
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225009, P. R. China.
Small. 2024 Jan;20(1):e2305548. doi: 10.1002/smll.202305548. Epub 2023 Aug 29.
2D metal-organic frameworks-based (2D MOF-related) materials benefit from variable topological structures, plentiful open active sites, and high specific surface areas, demonstrating promising applications in gas storage, adsorption and separation, energy conversion, and other domains. In recent years, researchers have innovatively designed multiple strategies to avoid the adverse effects of conventional methods on the synthesis of high-quality 2D MOFs. This review focuses on the latest advances in creative synthesis techniques for 2D MOF-related materials from both the top-down and bottom-up perspectives. Subsequently, the strategies are categorized and summarized for synthesizing 2D MOF-related composites and their derivatives. Finally, the current challenges are highlighted faced by 2D MOF-related materials and some targeted recommendations are put forward to inspire researchers to investigate more effective synthesis methods.
基于二维金属有机框架（与二维金属有机框架相关）的材料受益于可变的拓扑结构、丰富的开放活性位点和高比表面积，在气体存储、吸附与分离、能量转换及其他领域展现出广阔的应用前景。近年来，研究人员创新性地设计了多种策略，以避免传统方法对高质量二维金属有机框架合成产生的不利影响。本综述从自上而下和自下而上两个角度，聚焦于二维金属有机框架相关材料创新性合成技术的最新进展。随后，对合成二维金属有机框架相关复合材料及其衍生物的策略进行了分类和总结。最后，强调了二维金属有机框架相关材料目前面临的挑战，并提出了一些针对性建议，以激励研究人员探索更有效的合成方法。
