Analysis of the photocatalytic activity of LaSrFeCoO perovskite as a catalyst in the degradation of RB-5 dye.

The photocatalytic efficiency of some semiconductors depends mainly on their morphological, optical, and structural properties, which can be modified by varying the calcination temperature. In order to evaluate how these properties change, as a function of temperature in a AA'BB'O perovskite material, LaSrFeCoO (LSFC) was synthesized by the Pechini method and calcined at different temperatures (600 °C, 700 °C, 800 °C, and 900 °C). All the samples were characterized structurally, morphologically, and optically by XRD, SEM, and UV-Vis spectroscopy. Additionally, specific surface area and pore size distribution were calculated by BET and BHJ methods. LSFC was evaluated as photocatalyst material, estimating the degradation of reactive black 5 (RB5), employing as irradiation source UV light and sunlight. The obtained results display a clear tendency between the photoactivity and the heat treatment: degradation percentage decreases as the calcination temperature increases mainly due to the crystal and grain size and, furthermore, loss of porosity and the decrease in surface area, affecting the photocatalytic activity (98%, 95%, 74%, and 50% degradation, respectively). All the ceramic samples follow a pseudo-first-order reaction.