• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

基于过渡金属离子（铜、钴、铁）和3-氨基呋咱-4-羧酸的含能催化剂的设计、制备及燃烧性能

Design, preparation, and combustion performance of energetic catalysts based on transition metal ions (Cu, Co, Fe) and 3-aminofurazan-4-carboxylic acid.

作者信息

Liu Wei, Xu Yuangang, Zhang Yulong, Zheng Hanyue, Gou Xiaodong, Xiao Fei

机构信息

School of Environmental and Safety Engineering, North University of China Taiyuan Shanxi China

School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology Nanjing Jiangsu China

出版信息

RSC Adv. 2023 Sep 5;13(38):26563-26573. doi: 10.1039/d3ra03585a. eCollection 2023 Sep 4.

DOI:10.1039/d3ra03585a
PMID:37674483
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10477948/
Abstract

Development of energetic catalysts with high energy density and strong catalytic activity has become the focus and frontier of research, which is expected to improve the combustion performance and ballistic properties of solid propellants. In this work, three energetic catalysts, M(HO)(AFCA)·HO (AFCA = 3-aminofurazan-4-carboxylic acid, M = Cu, Co, Fe), are designed and synthesized based on the coordination reaction of transition metal ions and the energetic ligand. The target products are characterized by single crystal X-ray diffraction, Fourier transform infrared spectroscopy, differential thermal analysis, optical microscopy, and scanning electron microscopy. The results reveal that Cu(HO)(AFCA)·HO crystallizes in the monoclinic space group, = 1.918 g cm. Co(HO)(AFCA)·HO, and Fe(HO)(AFCA)·HO belong to orthorhombic space groups, their density is 1.886 g cm and 1.856 g cm, respectively. In addition, the designed catalysts show higher catalytic activity than some reported catalysts such as Co(en)(HBTI)]·en (HBTI = 4,5-bis(1-tetrazol-5-yl)-1-imida-zole), Co-AzT (HAzT = 5,5'-azotetrazole-1,1'-diol), and [Pb(BTF)(HO)] (BTF = 4,4'-oxybis [3,3'-(1-hydroxy-tetrazolyl)]furazan) for the thermal decomposition of ammonium perchlorate (AP). The high-temperature decomposition peak temperatures of AP/Cu(HO)(AFCA)·HO, AP/Co(HO)(AFCA)·HO, and AP/Fe(HO) (AFCA)·HO are decreased by 120.3 °C, 151.8 °C and 89.5 °C compared to the case of pure AP, while the heat release of them are increased by 768.8 J g, 780.5 J g, 750.9 J g, respectively. Moreover, the burning rates of solid propellants composed of AP/Cu(AFCA)(HO)·HO, AP/Co(AFCA)(HO)·HO and AP/Fe(AFCA)(HO)·HO are increased by 2.16 mm s, 2.53 mm s, and 1.57 mm s compared with the case of pure AP. This research shows considerable application prospects in improving the combustion and energy performance of solid propellants, it is also a reference for the design and preparation of other novel energetic catalysts.

摘要

开发具有高能量密度和强催化活性的含能催化剂已成为研究的重点和前沿领域，有望改善固体推进剂的燃烧性能和弹道性能。在本工作中，基于过渡金属离子与含能配体的配位反应，设计并合成了三种含能催化剂M(HO)(AFCA)·HO（AFCA = 3-氨基呋咱-4-羧酸，M = Cu、Co、Fe）。通过单晶X射线衍射、傅里叶变换红外光谱、差热分析、光学显微镜和扫描电子显微镜对目标产物进行了表征。结果表明，Cu(HO)(AFCA)·HO以单斜空间群结晶，密度为1.918 g/cm³。Co(HO)(AFCA)·HO和Fe(HO)(AFCA)·HO属于正交空间群，其密度分别为1.886 g/cm³和1.856 g/cm³。此外，所设计的催化剂对高氯酸铵（AP）热分解的催化活性高于一些已报道的催化剂，如Co(en)(HBTI)]·en（HBTI = 4,5-双(1-四唑-5-基)-1-咪唑）、Co-AzT（HAzT = 5,5'-偶氮四唑-1,1'-二醇）和[Pb(BTF)(HO)]（BTF = 4,4'-氧双[3,3'-(1-羟基四唑基)]呋咱）。与纯AP相比，AP/Cu(HO)(AFCA)·HO、AP/Co(HO)(AFCA)·HO和AP/Fe(HO)(AFCA)·HO的高温分解峰温度分别降低了120.3℃、151.8℃和89.5℃，而它们的热释放分别增加了768.8 J/g、780.5 J/g、750.9 J/g。此外，由AP/Cu(AFCA)(HO)·HO、AP/Co(AFCA)(HO)·HO和AP/Fe(AFCA)(HO)·HO组成的固体推进剂的燃速与纯AP相比分别提高了2.16 mm/s、2.53 mm/s和1.57 mm/s。本研究在改善固体推进剂的燃烧和能量性能方面显示出可观的应用前景，也为其他新型含能催化剂设计与制备提供了参考。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/edc71a967583/d3ra03585a-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/76418f9042b2/d3ra03585a-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/dddab383bb76/d3ra03585a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/ae66ec3ee124/d3ra03585a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/d2538646fbcf/d3ra03585a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/3c849d9c27c7/d3ra03585a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/d1b0898e5e81/d3ra03585a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/244f3b4c6ac3/d3ra03585a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/3c69ef05f6e6/d3ra03585a-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/5eb824261585/d3ra03585a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/8e265fa11b12/d3ra03585a-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/36ee1897edb8/d3ra03585a-s4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/61b23c3b4fa1/d3ra03585a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/36e82613257d/d3ra03585a-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/edc71a967583/d3ra03585a-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/76418f9042b2/d3ra03585a-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/dddab383bb76/d3ra03585a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/ae66ec3ee124/d3ra03585a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/d2538646fbcf/d3ra03585a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/3c849d9c27c7/d3ra03585a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/d1b0898e5e81/d3ra03585a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/244f3b4c6ac3/d3ra03585a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/3c69ef05f6e6/d3ra03585a-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/5eb824261585/d3ra03585a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/8e265fa11b12/d3ra03585a-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/36ee1897edb8/d3ra03585a-s4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/61b23c3b4fa1/d3ra03585a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/36e82613257d/d3ra03585a-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07ba/10477948/edc71a967583/d3ra03585a-f10.jpg

相似文献

1
Design, preparation, and combustion performance of energetic catalysts based on transition metal ions (Cu, Co, Fe) and 3-aminofurazan-4-carboxylic acid.基于过渡金属离子（铜、钴、铁）和3-氨基呋咱-4-羧酸的含能催化剂的设计、制备及燃烧性能
RSC Adv. 2023 Sep 5;13(38):26563-26573. doi: 10.1039/d3ra03585a. eCollection 2023 Sep 4.
2
Electrochemical Synthesis of the Energetic Combustion Catalyst Co(BODN)·9HO and Its Catalytic Effect on Ammonium Perchlorate Thermal Decomposition.高能燃烧催化剂Co(BODN)·9H₂O的电化学合成及其对高氯酸铵热分解的催化作用
Langmuir. 2023 Dec 5;39(48):17498-17512. doi: 10.1021/acs.langmuir.3c02768. Epub 2023 Nov 20.
3
Novel energetic metal-organic frameworks assembled from the energetic combination of furazan and tetrazole.由呋咱和四唑的高能组合组装而成的新型含能金属有机骨架。
Dalton Trans. 2020 May 19;49(19):6295-6301. doi: 10.1039/d0dt00862a.
4
Preparation of different morphology Cu/GO nanocomposites and their catalytic performance for thermal decomposition of ammonium perchlorate.不同形貌的Cu/GO纳米复合材料的制备及其对高氯酸铵热分解的催化性能
RSC Adv. 2022 Aug 15;12(35):22806-22814. doi: 10.1039/d2ra03772f. eCollection 2022 Aug 10.
5
growth of copper-based energetic complexes on GO and an MXene to synergistically promote the thermal decomposition of ammonium perchlorate.铜基含能配合物在氧化石墨烯和MXene上的生长以协同促进高氯酸铵的热分解。
Dalton Trans. 2023 Nov 28;52(46):17458-17469. doi: 10.1039/d3dt02686h.
6
Synthesis of Cu and Cd Metal-Organic Frameworks Based on 4,5-Bis(1-hydroxytetrazol-5-yl)-1,2,3-triazole and Their Effects as the Catalyst in Ammonium Perchlorate Thermal Decomposition.基于4,5-双(1-羟基四氮唑-5-基)-1,2,3-三唑的铜和镉金属有机框架的合成及其作为高氯酸铵热分解催化剂的作用
Inorg Chem. 2022 Nov 7;61(44):17485-17493. doi: 10.1021/acs.inorgchem.2c02384. Epub 2022 Oct 24.
7
Energetic bimetallic complexes as catalysts affect the thermal decomposition of ammonium perchlorate.作为催化剂的高能双金属配合物影响高氯酸铵的热分解。
Dalton Trans. 2022 Jun 27;51(25):9894-9904. doi: 10.1039/d2dt00593j.
8
Synthesis of Covalently Modified Energetic Graphene Oxide/CuO Composites with Enhanced Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate.具有增强催化高氯酸铵热分解性能的共价修饰氧化石墨烯/CuO复合材料的合成
ACS Omega. 2023 Jun 9;8(25):22876-22886. doi: 10.1021/acsomega.3c01865. eCollection 2023 Jun 27.
9
Enhanced thermal, safety and anti-hygroscopicity performance of core-shell ammonium perchlorate with a double coating layer.具有双重涂层的核壳高氯酸铵的热性能、安全性和抗吸湿性增强
Dalton Trans. 2023 Nov 28;52(46):17324-17339. doi: 10.1039/d3dt03068g.
10
Preparation of Zn-Co Bimetallic Catalysts and Their Catalytic Properties for Thermal Decomposition of Ammonium Perchlorate.锌钴双金属催化剂的制备及其对高氯酸铵热分解的催化性能
Langmuir. 2024 Jul 18. doi: 10.1021/acs.langmuir.4c00126.

本文引用的文献

1
Novel energetic metal-organic frameworks assembled from the energetic combination of furazan and tetrazole.由呋咱和四唑的高能组合组装而成的新型含能金属有机骨架。
Dalton Trans. 2020 May 19;49(19):6295-6301. doi: 10.1039/d0dt00862a.
2
Direct Growth of CuO Nanorods on Graphitic Carbon Nitride with Synergistic Effect on Thermal Decomposition of Ammonium Perchlorate.氧化铜纳米棒在石墨相氮化碳上的直接生长及其对高氯酸铵热分解的协同作用
Materials (Basel). 2017 May 2;10(5):484. doi: 10.3390/ma10050484.