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用于超级电容器应用的钼酸锶纳米带-碳混合材料。

MoS nanobelts-carbon hybrid material for supercapacitor applications.

作者信息

Khandare Lina N, Late Dattatray J, Chaure Nandu B

机构信息

Department of Physics, Savitribai Phule Pune University, Pune, India.

Centre for Nanoscience and Nanotechnology, Amity University Maharashtra, Mumbai, India.

出版信息

Front Chem. 2023 Aug 22;11:1166544. doi: 10.3389/fchem.2023.1166544. eCollection 2023.

DOI:10.3389/fchem.2023.1166544
PMID:37674526
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10477701/
Abstract

The MoS nanobelts/Carbon hybrid nanostructure was synthesized by the simple hydrothermal method. The MoS nanobelts were distributed in the interlayers of Lemon grass-derived carbon (LG-C), provides the active sites and avoid restacking of the sheets. The structural and morphological characterization of MoS/LG-C and LG-C were performed by Raman spectroscopy, X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. The electrochemical measurements were studied with cyclic voltammetry, the galvanostatic charge-discharge method, and electrochemical impedance spectroscopy. The specific capacitance of MoS/LG-C and LG-C exhibits 77.5 F g and 30.1 F g at a current density of 0.5 A g. The MoS/LG-C-based supercapacitor provided the maximum power density and energy density of 273.2 W kg and 2.1 Wh kg, respectively. Furthermore, the cyclic stability of MoS/LG-C was tested using charging-discharging up to 3,000 cycles, confirming only a 71.6% capacitance retention at a current density of 3 A g. The result showed that MoS/LG-C is a superior low-cost electrode material that delivered a high electrochemical performance for the next generation of electrochemical energy storage.

摘要

通过简单的水热法合成了二硫化钼纳米带/碳混合纳米结构。二硫化钼纳米带分布在柠檬草衍生碳(LG-C)的层间,提供活性位点并避免片层的重新堆叠。通过拉曼光谱、X射线衍射、场发射扫描电子显微镜、透射电子显微镜和X射线光电子能谱对二硫化钼/LG-C和LG-C进行了结构和形态表征。用电化学循环伏安法、恒电流充放电法和电化学阻抗谱进行了电化学测量。在电流密度为0.5 A g时,二硫化钼/LG-C和LG-C的比电容分别为77.5 F g和30.1 F g。基于二硫化钼/LG-C的超级电容器的最大功率密度和能量密度分别为273.2 W kg和2.1 Wh kg。此外,使用充放电测试了二硫化钼/LG-C高达3000次循环的循环稳定性,结果表明在电流密度为3 A g时电容保持率仅为71.6%。结果表明,二硫化钼/LG-C是一种优异的低成本电极材料,可为下一代电化学储能提供高电化学性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/6c43fa9c39c8/fchem-11-1166544-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/674375f01111/fchem-11-1166544-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/c883325c9f63/fchem-11-1166544-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/7d0b6395d75f/fchem-11-1166544-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/63b3bb7be16f/fchem-11-1166544-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/2985b0cd36b8/fchem-11-1166544-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/c7a7b31f22ff/fchem-11-1166544-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/cc576450020f/fchem-11-1166544-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/6c43fa9c39c8/fchem-11-1166544-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/674375f01111/fchem-11-1166544-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/c883325c9f63/fchem-11-1166544-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/7d0b6395d75f/fchem-11-1166544-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/63b3bb7be16f/fchem-11-1166544-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/2985b0cd36b8/fchem-11-1166544-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/c7a7b31f22ff/fchem-11-1166544-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/cc576450020f/fchem-11-1166544-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/956d/10477701/6c43fa9c39c8/fchem-11-1166544-g008.jpg

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