Bongu Chandra Sekhar, Arsalan Muhammad, Alsharaeh Edreese H
College of Science and General Studies, AlFaisal University, P.O. Box 50927, Riyadh 11533, Saudi Arabia.
EXPEC Advanced Research Center, Saudi Aramco, P.O. Box 5000, Dhahran 31311, Saudi Arabia.
ACS Omega. 2024 Mar 22;9(13):15294-15303. doi: 10.1021/acsomega.3c09877. eCollection 2024 Apr 2.
The nanocomposites of hexagonal boron nitride, molybdenum disulfide, and graphene (h-BN/G/MoS) are promising energy storage materials. The originality of the current work is the first-ever synthesis of 2D-layered ternary nanocomposites of boron nitrate, graphene, and molybdenum disulfide (h-BN/G/MoS) using ball milling and the sonication method and the investigation of their applicability for supercapacitor applications. The morphological investigation confirms the well-dispersed composite material production, and the ternary composite appears to be made of h-BN and MoS wrapping graphene. The electrochemical characterization of the prepared samples is evaluated by cyclic voltammetry and galvanostatic charge/discharge tests. With a high specific capacitance of 392 F g at a current density of 1 A g and an outstanding cycling stability with around 96.4% capacitance retention after 10,000 cycles, the ideal 5% BN_G@MoS_90@10 composite demonstrates exceptional capabilities. Furthermore, a symmetric supercapacitor (5% BN_G@MoS_90@10 composite) exhibits a 94.1% capacitance retention rate even after 10,000 cycles, an energy density of 16.4 W h kg, and a power density of 501 W kg. The findings show that the preparation procedure is safe for the environment, manageable, and suitable for mass production, which is crucial for advancing the electrode materials used in supercapacitors.
六方氮化硼、二硫化钼和石墨烯的纳米复合材料(h-BN/G/MoS₂)是很有前景的储能材料。当前工作的创新性在于首次使用球磨和超声法合成了硝酸硼、石墨烯和二硫化钼的二维层状三元纳米复合材料(h-BN/G/MoS₂),并研究了它们在超级电容器应用中的适用性。形态学研究证实了复合材料的良好分散性,三元复合材料似乎是由h-BN和MoS₂包裹石墨烯制成。通过循环伏安法和恒电流充/放电放电测试测试对制备样品进行电化学表征。理想的5% BN_G@MoS₉₀@1₀复合材料在1 A g⁻¹的电流密度下具有392 F g⁻¹的高比电容,在10000次循环后具有约96.4%的电容保持率,表现出出色的循环稳定性。此外,对称超级电容器(5% BN_G@MoS₉₀@1₀复合材料)即使在10000次循环后仍具有94.1%的电容保持率,能量密度为16.4 W h kg⁻¹,功率密度为501 W kg⁻¹。研究结果表明,该制备过程对环境安全、易于管理且适合大规模生产,这对于推进超级电容器中使用的电极材料至关重要。