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用于高性能超级电容器应用的SbO-MoS纳米复合材料的制备与表征

Fabrication and characterization of SbO-MoSnanocomposites for high performance supercapacitor applications.

作者信息

K Dhamodharan, Singh Abhishek Kumar

机构信息

Department of Physics, School of Advanced Sciences, Vellore Institute of Technology, Vellore, Tamil Nadu 632014, India.

出版信息

Nanotechnology. 2024 Aug 12;35(43). doi: 10.1088/1361-6528/ad6995.

DOI:10.1088/1361-6528/ad6995
PMID:39084237
Abstract

Binary nanocomposite-based electrodes have been studied extensively in recent times owing to their multiple oxidation states, excellent physico-chemical features, and combined morphology, which are suitable for increasing the electrochemical performance of supercapacitors. The present work deals with SbO-MoSnanocomposites electrode for supercapacitor applications. The x-ray diffraction (XRD), Raman, scanning electron microscope (SEM), energy dispersive x-ray (EDX), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and x-ray photoelectron spectroscopy (XPS) characterizations have been studied to analyze the phase formation, vibrational modes, morphology, elemental composition and binding energies of the prepared SbO-MoSnanocomposites electrode material, as well as their electrochemical measurements such as cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS) have been analyzed. The developed SbO-MoSnanocomposites electrode provides a high specific capacitance of 454.3 F gat the current density of 1 A g. Further, the hybrid supercapacitor device has been constructed which shows 104.04 F gof specific capacitance at 2 A gand manifests a good energy density of 24.42 Wh kgat a power density of 1299.89 W kg. Additionally, the hybrid device SbO-MoS//AC exhibits a good capacitive retention of 90.6% and a coulombic efficiency of 100.45% at 10 A gover 8000 cycles.

摘要

近年来,基于二元纳米复合材料的电极因其多种氧化态、优异的物理化学特性和复合形态而得到广泛研究,这些特性适用于提高超级电容器的电化学性能。目前的工作涉及用于超级电容器应用的SbO-MoS纳米复合材料电极。已对X射线衍射(XRD)、拉曼光谱、扫描电子显微镜(SEM)、能量色散X射线(EDX)、高分辨率透射电子显微镜(HRTEM)、选区电子衍射(SAED)和X射线光电子能谱(XPS)进行了表征研究,以分析所制备的SbO-MoS纳米复合材料电极材料的相形成、振动模式、形态、元素组成和结合能,并且对其电化学测量,如循环伏安法(CV)、恒电流充放电(GCD)和电化学阻抗谱(EIS)进行了分析。所开发的SbO-MoS纳米复合材料电极在1 A g的电流密度下提供了454.3 F g的高比电容。此外,构建了混合超级电容器装置,该装置在2 A g时显示出104.04 F g的比电容,并且在1299.89 W kg的功率密度下表现出24.42 Wh kg的良好能量密度。此外,混合装置SbO-MoS//AC在10 A g下经过8000次循环后表现出90.6%的良好电容保持率和100.45%的库仑效率。

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