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Catalytic cascade synthesis of cyanohydrin esters water/O-induced cyanide transfer from KFe(CN).

作者信息

Singh Anupam Kumar, Chauhan Shivani Singh, Bhadra Sukalyan

机构信息

Inorganic Materials and Catalysis Division, CSIR-Central Salt and Marine Chemicals Research Institute, G.B. Marg, Bhavnagar, Gujarat 364002, India.

Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India.

出版信息

Chem Commun (Camb). 2023 Sep 26;59(77):11544-11547. doi: 10.1039/d3cc02743k.

DOI:10.1039/d3cc02743k
PMID:37675779
Abstract

The copper-catalyzed α-oxygenation of aryl benzyl ketones is merged with a unique water/O-induced release of cyanide ions from KFe(CN) and a benzil-cyanide reaction. This strategy gives expedient access to cyanohydrin esters starting directly from broadly accessible aryl benzyl ketones. The cyanide release strategy was further integrated with a copper catalyzed oxygenation-decarbonylation sequence to produce cyanohydrin esters from 1,3-diketones.

摘要

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