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基于热解油的固体油料环境影响评估

Assessment of the Environmental Impact of Solid Oil Materials Based on Pyrolysis Oil.

作者信息

Staroń Anita, Kijania-Kontak Magda, Dziadas Mariusz, Banach Marcin

机构信息

Department of Engineering and Chemical Technology, Cracow University of Technology, 24 Warszawska St., 31-155 Cracow, Poland.

Department of Civil Engineering, Cracow University of Technology, 24 Warszawska St., 31-155 Cracow, Poland.

出版信息

Materials (Basel). 2023 Aug 26;16(17):5847. doi: 10.3390/ma16175847.

Abstract

One method of managing used car tires is decomposition by thermochemical conversion methods. By conducting the process at temperatures of 450-750 °C, three fractions are obtained from tires: oil, gas, and solid. The liquid product of the pyrolysis of used car tires is pyrolysis oil, which consists of aromatic, polyaromatic, and aliphatic hydrocarbons. Unconventional building materials were obtained from tire pyrolysis oil and the environmental impact was evaluated. Blocks made from pyrolysis oil showed mechanical strength of up to about 1700 N. No heavy metals or polycyclic aromatic hydrocarbons, which were found in the crude heavy-PO fraction, were detected in the filtrates after incubation of the block obtained from the heavy-PO fraction at 240 °C. The highest inhibition of shoot (74.4%) and root (57.5%) growth was observed for solid materials from the medium-PO fraction obtained at 240 °C. The most favorable values of the parameters for the process of obtaining blocks based on post-PO were an annealing temperature of 180 °C, time of 20 h, and mass ratio of catalyst to catalyzed oil of 0.045.

摘要

管理废旧汽车轮胎的一种方法是通过热化学转化方法进行分解。在450 - 750°C的温度下进行该过程时,轮胎可得到三种馏分:油、气和固体。废旧汽车轮胎热解的液体产物是热解油,它由芳香烃、多环芳烃和脂肪烃组成。从轮胎热解油中获得了非常规建筑材料,并对其环境影响进行了评估。由热解油制成的砖块显示出高达约1700 N的机械强度。在将从重质热解油馏分获得的砖块在240°C下孵育后的滤液中,未检测到在粗重质热解油馏分中发现的重金属或多环芳烃。对于在240°C下获得的中质热解油馏分的固体材料,观察到对芽(74.4%)和根(57.5%)生长的抑制作用最强。基于热解油后产物制备砖块过程中,最有利的参数值为退火温度180°C、时间20小时以及催化剂与被催化油的质量比0.045。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00b9/10488463/18e5982de3ba/materials-16-05847-g001.jpg

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