μ-1,6-二氧代-1,6-二苯基己烷-3,4-二醇双-[(2,2'-联吡啶)-氯合铜(II)]二水合物
μ-1,6-Dioxo-1,6-di-phenyl-hexane-3,4-diolato-bis-[(2,2'-bi-pyridine)-chlorido-copper(II)] dihydrate.
作者信息
Nye Luke, Telfer Shane G, Turnbull Mark M
机构信息
Carlson School of Chemistry and Biochemistry, Clark University, 950 Main St., Worcester, MA 01610, USA.
School of Natural Sciences, Institute of Fundamental Sciences, Massey University, Palmerston North, New Zealand.
出版信息
IUCrdata. 2023 Aug 30;8(Pt 8):x230713. doi: 10.1107/S2414314623007137. eCollection 2023 Aug.
The reaction of CuCl with 1,6-diphenyl-1,3,5,6-hexa-netetrone and 2,2'-bi-pyridine (bipy) in ethanol gave crystals of the corresponding bimetallic complex, [Cu(CHO)Cl(CHN)]·2HO. The mol-ecule is centrosymmetric with each Cu ion coordinated to two oxygen atoms from the tetronediate, two nitro-gen atoms from a bipy ligand and one coordinated chloride ion. A water mol-ecule of crystallization forms hydrogen bonds to the chloride ions, linking the mol-ecules into a chain parallel to the -face diagonal.
氯化铜（CuCl）与1,6 - 二苯基 - 1,3,5,6 - 己四酮和2,2'-联吡啶（bipy）在乙醇中反应生成了相应双金属配合物[Cu(CHO)Cl(CHN)]·2HO的晶体。该分子具有中心对称性，每个铜离子与四酮二酸酯中的两个氧原子、联吡啶配体中的两个氮原子以及一个配位氯离子配位。一个结晶水分子与氯离子形成氢键，将分子连接成平行于晶面角线的链状结构。
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