Department of Chemistry, University of Management and Technology (UMT), Sialkot Campus, 51310, Pakistan.
Department of Botany, GC University, Lahore 54000, Pakistan.
Int J Biol Macromol. 2023 Dec 31;253(Pt 3):126885. doi: 10.1016/j.ijbiomac.2023.126885. Epub 2023 Sep 12.
In this research paper, a novel process was developed for reactive printing of cotton fabric, with the objective of producing a high-quality printed fabric that is sustainable, eco-friendly, and low-cost which will ultimately reduce the impact of climate change. The study incorporated substituted tamarind polysaccharide (STP) obtained from agricultural waste, trichloro-ethanoic acid (TCEA), and polyethylene glycol (PEG-400) in the reactive printing paste. Tamarind starch was extracted from the seeds having 72 % yield, and substitution was performed to use it as a thickener in the printing paste. The conventional printing system was formulated with sodium alginate, urea, and sodium bicarbonate at dose levels of 2 %, 15 %, and 2.5 %, respectively, while the modified recipe was formulated with STP and TCEA at 5 % and 3 % dose levels, respectively along with varying doses of PEG-400 (0 %, 1 %, and 2 %) in novel prints. Various factors such as shade comparison, penetration, staining on the white ground, washing, rubbing, light and perspiration fastness, sharpness of edges, and fabric hardness were evaluated for all the recipes. The study demonstrated that the optimal outcomes were obtained with a 2 % PEG-400 dose level. This study represents a significant contribution to sustainable textile production, as tamarind agriculture waste was used as a raw material, which is an environmentally friendly alternative of sodium alginate that reduces the wastewater load. Additionally, PEG-400 was utilized as a nitrogen-free solubilizing moisture management substitution of urea for printing, while TCEA dissociated at high temperature to make alkaline pH during curing of the printed fabric to replace sodium bicarbonate. This research is a novel contribution to the printing industry, as these three constituents have not been previously used together other than this research group, in the history of reactive printing.
在本研究论文中,开发了一种用于棉织物反应性印花的新工艺,旨在生产高质量的印花织物,该织物可持续、环保且低成本,最终将减少气候变化的影响。该研究在反应性印花浆中加入了从农业废弃物中提取的替代罗望子多糖(STP)、三氯乙酸(TCEA)和聚乙二醇(PEG-400)。从种子中提取罗望子淀粉,收率为 72%,并进行取代,将其用作印花浆中的增稠剂。传统的印花系统由海藻酸钠、尿素和碳酸氢钠以 2%、15%和 2.5%的剂量水平配制,而改良配方则由 STP 和 TCEA 以 5%和 3%的剂量水平配制,同时在新型印花中加入不同剂量的 PEG-400(0%、1%和 2%)。对所有配方进行了色差值比较、渗透性、白地染色、洗涤、摩擦、耐光和汗渍牢度、边缘清晰度和织物硬度等评估。研究表明,在 2%PEG-400 剂量水平下获得了最佳结果。本研究代表了对可持续纺织生产的重大贡献,因为罗望子农业废弃物被用作原料,这是海藻酸钠的环保替代品,可以减少废水负荷。此外,PEG-400 被用作无氮增溶水分管理替代物,替代了印花中的尿素,而 TCEA 在高温下解离,在印花织物的固化过程中形成碱性 pH 值,以替代碳酸氢钠。这项研究是印花行业的一项新贡献,因为除了本研究小组之外,这三种成分以前从未在反应性印花中一起使用过。