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用于室温气体传感应用的纯SnO薄膜的不相容性

Incompatibility of Pure SnO Thin Films for Room-Temperature Gas Sensing Application.

作者信息

Thomas Anju, Thirumalaisamy Logu, Madanagurusamy Sridharan, Sivaperuman Kalainathan

机构信息

School of Advanced Sciences, Vellore Institute of Technology, Vellore 632014, India.

Dept. of Physics, G.T.N Arts College (Affiliated to Madurai Kamaraj University), Madurai, Tamil Nadu 625021, India.

出版信息

ACS Omega. 2023 Aug 30;8(36):32848-32854. doi: 10.1021/acsomega.3c04038. eCollection 2023 Sep 12.

Abstract

Despite the high sensitivity and selectivity, the high operating temperature required for activation energy of tin oxide (SnO) still stands as a drawback for SnO based gas sensors. In this work, the SnO thin films were deposited through spray pyrolysis and were subjected to gas sensing at 27 °C (room temperature) towards different gases. The films exhibited a consistently low response of approximately 1 when tested to various VOCs. The type, concentration, and mobility of charge carriers were determined from the Hall measurements. The high carrier concentration accompanied by poor mobility and grain boundary scattering is supposed to hinder its performance at room temperature. The obtained film had spherical morphology, which lead to grain boundary scatterings and decreased the mobility of carriers.

摘要

尽管氧化锡(SnO)气体传感器具有高灵敏度和高选择性,但激活能所需的高工作温度仍然是基于SnO的气体传感器的一个缺点。在这项工作中,通过喷雾热解沉积了SnO薄膜,并在27°C(室温)下对不同气体进行气敏测试。当测试各种挥发性有机化合物时,这些薄膜表现出始终约为1的低响应。通过霍尔测量确定了载流子的类型、浓度和迁移率。高载流子浓度伴随着低迁移率和晶界散射,这被认为会阻碍其在室温下的性能。所获得的薄膜具有球形形态,这导致了晶界散射并降低了载流子的迁移率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3230/10500894/c136a5fd0304/ao3c04038_0002.jpg

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