Sun Haibo, Qin Pufeng, Liang Yunshan, Yang Yuan, Zhang Jiachao, Guo Jiayin, Hu Xiaolong, Jiang Yi, Zhou Yunfei, Luo Lin, Wu Zhibin
College of Environment and Ecology, Hunan Agricultural University, Changsha 410128, PR China; Key Laboratory for Rural Ecosystem Health in the Dongting Lake Area of Hunan Province, Changsha 410128, PR China.
College of Environment and Ecology, Hunan Agricultural University, Changsha 410128, PR China; Key Laboratory for Rural Ecosystem Health in the Dongting Lake Area of Hunan Province, Changsha 410128, PR China.
Ultrason Sonochem. 2023 Nov;100:106600. doi: 10.1016/j.ultsonch.2023.106600. Epub 2023 Sep 18.
Recently, bismuth (Bi)-based photocatalysts have been a well-deserved hotspot in the field of photocatalysis owning to their photoelectrochemical properties driven by the distortion of the Bi 6 s orbital, while their narrow band gap and poor quantum efficiency still restrict their application. With the development of ultrasonic technology, it is expected to become a broom to clear the application obstacles of Bi-based photocatalysts. The special forces and environmental conditions brought by ultrasonic irradiation play beneficial roles in the preparation, modification and performance releasement of Bi-based photocatalysts. In this review, the role and influencing factors of ultrasound in the preparation and modification of Bi-based photocatalysts were introduced. Crucially, the mechanism of the improving the performance for various types of Bi-based photocatalysts by ultrasound in the whole process of photocatalysis was deeply analyzed. Then, the application of ultrasonic synergistic Bi-based photocatalysts in contaminants treatment and energy conversion was briefly introduced. Finally, based on an unambiguous understanding of ultrasonic technology in assisting Bi-based photocatalysts, the future directions and possibilities for ultrasonic synergistic Bi-based photocatalysts are explored.
近年来,铋(Bi)基光催化剂凭借其由Bi 6s轨道畸变驱动的光电化学性质,在光催化领域成为当之无愧的研究热点,然而其窄带隙和低量子效率仍限制了它们的应用。随着超声技术的发展,有望成为扫除铋基光催化剂应用障碍的一把扫帚。超声辐照带来的特殊作用力和环境条件,在铋基光催化剂的制备、改性及性能释放方面发挥着有益作用。本文综述了超声在铋基光催化剂制备和改性中的作用及影响因素。关键的是,深入分析了超声在光催化全过程中提高各类铋基光催化剂性能的作用机制。然后,简要介绍了超声协同铋基光催化剂在污染物处理和能量转换方面的应用。最后,基于对超声技术辅助铋基光催化剂的明确认识,探索了超声协同铋基光催化剂未来的发展方向和可能性。