Wei Dan, Cao Xiaoyu, Ma Miaomiao, Zhao Zexiang, Zhang Jing, Dong Xinyu, Wang Chengbing
School of Materials Science and Engineering Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials Shaanxi University of Science and Technology Xi'an Shaanxi 710021 China.
Glob Chall. 2023 Jul 5;7(9):2300046. doi: 10.1002/gch2.202300046. eCollection 2023 Sep.
Taking abundant and sustainable solar energy as the only energy source, solar-powered interface evaporation has been regarded as a promising method to alleviate the pressure of freshwater shortage. However, the uptake of clean water from brine is constantly accompanied by evaporation of water and condensation of vapor, which inevitably generates salt solid, preventing further continuous and stable evaporation. The most direct method is to fabricate a photothermal material with salt self-resistance by using the reflux of salt ions. Here, a superhydrophilic interconnected biomass carbon absorber (SBCA) is prepared by freeze-drying and carbonization, realizing strong liquid pumping, and self-blocking salt. In combination with superior broadband light absorption (94.91%), high porosity (95.9%), superhydrophilicity, and excellent thermal localization, an evaporation device with excellent evaporation rate (2.45 kg m h under 1 kW m) is successfully proposed. In the meantime, the porous skeleton and rapid water transport can enhance the diffusion of salt ions and slow down the rate of salt deposition. As a result, no salt deposition is found on the SBCA surface after continuous irradiation at 1 kW m for 15 h. The design can provide a convenient and low-cost efficient strategy for solar steam generators to address clean water acquisition.
以丰富且可持续的太阳能作为唯一能源,太阳能界面蒸发被视为缓解淡水短缺压力的一种有前景的方法。然而,从盐水中获取清洁水的过程始终伴随着水的蒸发和蒸汽的凝结,这不可避免地会产生盐固体,从而阻碍进一步持续稳定的蒸发。最直接的方法是利用盐离子回流制备具有抗盐性能的光热材料。在此,通过冷冻干燥和碳化制备了一种超亲水互连生物质碳吸收体(SBCA),实现了强大的液体泵送和自阻盐功能。结合优异的宽带光吸收(94.91%)、高孔隙率(95.9%)、超亲水性和出色的热局域化特性,成功提出了一种具有优异蒸发速率(在1 kW m下为2.45 kg m² h)的蒸发装置。同时,多孔骨架和快速的水传输可以增强盐离子的扩散并减缓盐沉积速率。结果,在1 kW m下连续照射15小时后,SBCA表面未发现盐沉积。该设计可为太阳能蒸汽发生器获取清洁水提供一种便捷且低成本的高效策略。