Organic Semiconductor Centre, SUPA, School of Physics and Astronomy, University of St Andrews, St Andrews, UK.
WestCHEM, School of Chemistry, University of Glasgow, Glasgow, UK.
Nature. 2023 Sep;621(7980):746-752. doi: 10.1038/s41586-023-06488-5. Epub 2023 Sep 27.
Organic semiconductors are carbon-based materials that combine optoelectronic properties with simple fabrication and the scope for tuning by changing their chemical structure. They have been successfully used to make organic light-emitting diodes (OLEDs, now widely found in mobile phone displays and televisions), solar cells, transistors and sensors. However, making electrically driven organic semiconductor lasers is very challenging. It is difficult because organic semiconductors typically support only low current densities, suffer substantial absorption from injected charges and triplets, and have additional losses due to contacts. In short, injecting charges into the gain medium leads to intolerable losses. Here we take an alternative approach in which charge injection and lasing are spatially separated, thereby greatly reducing losses. We achieve this by developing an integrated device structure that efficiently couples an OLED, with exceptionally high internal-light generation, with a polymer distributed feedback laser. Under the electrical driving of the integrated structure, we observe a threshold in light output versus drive current, with a narrow emission spectrum and the formation of a beam above the threshold. These observations confirm lasing. Our results provide an organic electronic device that has not been previously demonstrated, and show that indirect electrical pumping by an OLED is a very effective way of realizing an electrically driven organic semiconductor laser. This provides an approach to visible lasers that could see applications in spectroscopy, metrology and sensing.
有机半导体是基于碳的材料,它们将光电性能与简单的制造工艺以及通过改变化学结构进行调谐的能力结合在一起。它们已成功用于制造有机发光二极管(OLED,现在广泛用于手机显示屏和电视机)、太阳能电池、晶体管和传感器。然而,制造电驱动的有机半导体激光器极具挑战性。这是因为有机半导体通常仅支持低电流密度,会受到注入电荷和三重态的大量吸收,并且由于接触还会有其他损耗。简而言之,将电荷注入增益介质会导致不可容忍的损耗。在这里,我们采用了一种替代方法,其中电荷注入和激光发射是空间分离的,从而大大降低了损耗。我们通过开发一种集成器件结构来实现这一点,该结构可以有效地将具有极高内部光生成效率的 OLED 与聚合物分布式反馈激光器耦合。在集成结构的电驱动下,我们观察到光输出与驱动电流之间的阈值,具有较窄的发射光谱和阈值以上光束的形成。这些观察结果证实了激光的存在。我们的结果提供了一种以前未被证明的有机电子器件,并表明 OLED 的间接电泵浦是实现电驱动有机半导体激光器的一种非常有效的方法。这为可见激光提供了一种可能在光谱学、计量学和传感中得到应用的方法。