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用于锌空气电池的(铁-钴-镍-锌)基金属有机框架衍生电催化剂

(Fe-Co-Ni-Zn)-Based Metal-Organic Framework-Derived Electrocatalyst for Zinc-Air Batteries.

作者信息

Adhikari Anup, Chhetri Kisan, Rai Rajan, Acharya Debendra, Kunwar Jyotendra, Bhattarai Roshan Mangal, Jha Rupesh Kumar, Kandel Dasharath, Kim Hak Yong, Kandel Mani Ram

机构信息

Central Department of Chemistry, Tribhuvan University, Kathmandu 44618, Nepal.

Department of Nano Convergence Engineering, Jeonbuk National University, Jeonju 561-756, Republic of Korea.

出版信息

Nanomaterials (Basel). 2023 Sep 21;13(18):2612. doi: 10.3390/nano13182612.

Abstract

Zinc-air batteries (ZABs) have garnered significant interest as a viable substitute for lithium-ion batteries (LIBs), primarily due to their impressive energy density and low cost. However, the efficacy of zinc-air batteries is heavily dependent on electrocatalysts, which play a vital role in enhancing reaction efficiency and stability. This scholarly review article highlights the crucial significance of electrocatalysts in zinc-air batteries and explores the rationale behind employing Fe-Co-Ni-Zn-based metal-organic framework (MOF)-derived hybrid materials as potential electrocatalysts. These MOF-derived electrocatalysts offer advantages such as abundancy, high catalytic activity, tunability, and structural stability. Various synthesis methods and characterization techniques are employed to optimize the properties of MOF-derived electrocatalysts. Such electrocatalysts exhibit excellent catalytic activity, stability, and selectivity, making them suitable for applications in ZABs. Furthermore, they demonstrate notable capabilities in the realm of ZABs, encompassing elevated energy density, efficacy, and prolonged longevity. It is imperative to continue extensively researching and developing this area to propel the advancement of ZAB technology forward and pave the way for its practical implementation across diverse fields.

摘要

锌空气电池(ZABs)作为锂离子电池(LIBs)的一种可行替代品,已引起了广泛关注,这主要归功于其令人印象深刻的能量密度和低成本。然而,锌空气电池的效能在很大程度上依赖于电催化剂,电催化剂在提高反应效率和稳定性方面起着至关重要的作用。这篇学术综述文章强调了电催化剂在锌空气电池中的关键意义,并探讨了采用铁钴镍锌基金属有机框架(MOF)衍生的混合材料作为潜在电催化剂的基本原理。这些MOF衍生的电催化剂具有丰富性、高催化活性、可调节性和结构稳定性等优点。采用了各种合成方法和表征技术来优化MOF衍生电催化剂的性能。这类电催化剂表现出优异的催化活性、稳定性和选择性,使其适用于锌空气电池。此外,它们在锌空气电池领域展现出显著的能力,包括提高能量密度、效能和延长使用寿命。必须继续广泛研究和开发该领域,以推动锌空气电池技术的进步,并为其在各个领域的实际应用铺平道路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a272/10534837/3eb1cd1e8986/nanomaterials-13-02612-g002.jpg

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