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一种使用衍生先进材料进行环境污染管理/修复技术的新方法。

A novel approach to environmental pollution management/remediation techniques using derived advanced materials.

作者信息

Singh Rashmi, Samuel Melvin S, Ravikumar Madhumita, Ethiraj Selvarajan, Kirankumar V S, Kumar Mohanraj, Arulvel R, Suresh Sagadevan

机构信息

Department of Physics, Institute of Applied Sciences and Humanities, GLA University, Mathura, Uttar Pradesh, 281406, India.

Department of Bioengineering, Saveetha School of Engineering, Saveetha Institute of Medical and Technical, Chennai, 602105, India; Department of Civil, Construction, and Environmental Engineering, Marquette University, Milwaukee, WI, 53233, United States.

出版信息

Chemosphere. 2023 Dec;344:140311. doi: 10.1016/j.chemosphere.2023.140311. Epub 2023 Sep 26.

Abstract

The carbon dioxide (CO) crisis is one of the world's most urgent issues. Meeting the worldwide targets set for CO capture and storage (CCS) is crucial. Because it may significantly reduce energy consumption compared to traditional amine-based adsorption capture, adsorption dependant CO capture is regarded as one of the most hopeful techniques in this paradigm. The expansion of unique, critical edge adsorbent materials has received most of the research attention to date, with the main objective of improving adsorption capacity and lifespan while lowering the temperature of adsorption, thereby lowering the energy demand of sorbent revival. There are specific materials needed for each step of the carbon cycle, including capture, regeneration, and conversion. The potential and efficiency of metal-organic frameworks (MOFs) in overcoming this obstacle have recently been proven through research. In this study, we pinpoint MOFs' precise structural and chemical characteristics that have contributed to their high capture capacity, effective regeneration and separation processes, and efficient catalytic conversions. As prospective materials for the next generation of energy storage and conversion applications, carbon-based compounds like graphene, carbon nanotubes, and fullerenes are receiving a lot of interest. Their distinctive physicochemical characteristics make them suitable for these popular study topics, including structural stability and flexibility, high porosity, and customizable physicochemical traits. It is possible to precisely design the interior of MOFs to include coordinatively unsaturated metal sites, certain heteroatoms, covalent functionalization, various building unit interactions, and integrated nanoscale metal catalysts. This is essential for the creation of MOFs with improved performance. Utilizing the accuracy of MOF chemistry, more complicated materials must be built to handle selectivity, capacity, and conversion all at once to achieve a comprehensive solution. This review summarizes, the most recent developments in adsorption-based CO combustion capture, the CO adsorption capacities of various classes of solid sorbents, and the significance of advanced carbon nanomaterials for environmental remediation and energy conversion. This review also addresses the difficulties and potential of developing carbon-based electrodes for energy conversion and storage applications.

摘要

二氧化碳(CO)危机是全球最紧迫的问题之一。实现全球设定的二氧化碳捕集与封存(CCS)目标至关重要。由于与传统的基于胺的吸附捕集相比,它可能显著降低能源消耗,因此依赖吸附的二氧化碳捕集被视为该范例中最有前景的技术之一。迄今为止,独特的关键边缘吸附剂材料的扩展受到了大部分研究关注,主要目标是提高吸附容量和寿命,同时降低吸附温度,从而降低吸附剂再生的能源需求。碳循环的每个步骤都需要特定的材料,包括捕集、再生和转化。金属有机框架(MOF)在克服这一障碍方面的潜力和效率最近已通过研究得到证实。在本研究中,我们确定了MOF的精确结构和化学特性,这些特性有助于其高捕集能力、有效的再生和分离过程以及高效的催化转化。作为下一代储能和转化应用的潜在材料,石墨烯、碳纳米管和富勒烯等碳基化合物正受到广泛关注。它们独特的物理化学特性使其适用于这些热门研究课题,包括结构稳定性和灵活性、高孔隙率以及可定制的物理化学特性。可以精确设计MOF的内部结构,使其包含配位不饱和金属位点、某些杂原子、共价功能化、各种建筑单元相互作用以及集成的纳米级金属催化剂。这对于创建性能改进的MOF至关重要。利用MOF化学的精确性,必须构建更复杂的材料,以便同时处理选择性、容量和转化问题,从而实现全面的解决方案。本综述总结了基于吸附的二氧化碳燃烧捕集的最新进展、各类固体吸附剂的二氧化碳吸附容量,以及先进碳纳米材料在环境修复和能量转化中的重要性。本综述还讨论了开发用于能量转化和存储应用的碳基电极的困难和潜力。

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