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在炼油厂环境下承包活动中(2008-2018 年)总颗粒物、六价铬和锰的焊接烟尘接触水平和控制。

Levels and control of welding fume exposure to total particulate, hexavalent chromium, and manganese in contracted activities in an oil refinery setting (2008-2018).

机构信息

Shell USA Inc, Houston, Texas.

Shell Chemical LP, Geismar, Louisiana.

出版信息

J Occup Environ Hyg. 2024 Jan;21(1):35-46. doi: 10.1080/15459624.2023.2264350. Epub 2023 Nov 1.

Abstract

In response to increasing focus on occupational exposures to welding fume, a 10-year series of personal exposure measurements was analyzed for the two main welding processes (Shielded Metal Arc Welding or Stick and Tungsten Inert Gas welding or TIG) used in an oil refinery setting. Exposures from ancillary gouging and grinding were also analyzed. The operations were conducted under a permit-to-work system, which stipulated control measures in the form of ventilation and respiratory protective equipment (RPE) depending on the work environment, base metal, and welding process. The analysis focused on three health hazards of interest: total particulate (TP); hexavalent chromium (Cr (VI)); and manganese (Mn). The study's aims were the analysis of exposure levels related to operational conditions to verify the adequacy of required control measures and the generation of quantitative information for the development of predictive exposure models. Arithmetic mean exposures were 2.01 mg/m for TP ( = 94), 13.86 µg/m for Cr (VI) ( = 160), and 0.024 mg/m for Mn ( = 95). Requirements and practices for ventilation and use of RPE appeared adequate for maintaining exposure levels below maximum use concentrations. Predictive models for mean exposure levels were developed using multiple linear regression. Different patterns emerged for TP, Cr (VI), and Mn exposure determinants. Enclosed or confined work environments were associated with elevated exposure levels, regardless of the provision of local exhaust or general dilution ventilation. Carbon arc, used with gouging and grinding, contributed significantly to TP exposure ( = 0.006). The relative TP source strengths of the two main welding processes were comparable to the literature data. For Cr (VI), stick welding was associated with approximately 50-fold ( < 0.001) higher exposure potential than TIG welding. For Mn, this difference was approximately 2.5-fold. Differences were observed across the three analytes in exposure reduction efficiency of local exhaust ventilation (LEV) compared to natural ventilation, possibly due to ineffective use in confined spaces. These findings contribute to the overall understanding of TP, Cr (VI), and Mn exposures from welding and required controls in an oil refinery setting.

摘要

针对越来越多的对焊接烟尘职业暴露的关注,对某炼油厂使用的两种主要焊接工艺( Shielded Metal Arc Welding 或 Stick 和 Tungsten Inert Gas welding 或 TIG)进行了为期 10 年的个人暴露测量系列分析。还分析了辅助气刨和打磨产生的暴露。这些操作是在工作许可证制度下进行的,该制度根据工作环境、母材和焊接工艺,以通风和呼吸防护设备 (RPE) 的形式规定了控制措施。分析主要集中在三个感兴趣的健康危害上:总颗粒物 (TP);六价铬 (Cr (VI));和锰 (Mn)。该研究的目的是分析与操作条件相关的暴露水平,以验证所需控制措施的充分性,并为开发预测性暴露模型生成定量信息。总颗粒物的算术平均值暴露量为 2.01 mg/m(= 94),六价铬的暴露量为 13.86 µg/m(= 160),锰的暴露量为 0.024 mg/m(= 95)。通风和使用呼吸防护设备的要求和实践似乎足以将暴露水平保持在最高使用浓度以下。使用多元线性回归为平均暴露水平开发了预测模型。总颗粒物、六价铬和锰暴露决定因素呈现出不同的模式。无论是否提供局部排气或一般稀释通风,封闭或封闭的工作环境都会导致暴露水平升高。碳弧气刨,用于气刨和打磨,对总颗粒物暴露有显著贡献(= 0.006)。两种主要焊接工艺的总颗粒物相对源强度与文献数据相当。对于六价铬,与 TIG 焊接相比, stick 焊接与大约 50 倍(<0.001)的更高暴露潜力相关。对于锰,这种差异约为 2.5 倍。在三种分析物中,局部排气通风 (LEV) 的暴露减少效率存在差异,与自然通风相比,这可能是由于在封闭空间中使用效果不佳。这些发现有助于全面了解炼油厂环境中焊接和所需控制的总颗粒物、六价铬和锰暴露。

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