Duraes Anderson D S, Gezelter J Daniel
Department of Chemistry and Biochemistry, University of Notre Dame, 251 Nieuwland Science Hall, Notre Dame, Indiana 46556, USA.
J Chem Phys. 2023 Oct 7;159(13). doi: 10.1063/5.0152546.
We present a theory for pitch, a matrix property that is linked to the coupling of rotational and translational motion of rigid bodies at low Reynolds numbers. The pitch matrix is a geometric property of objects in contact with a surrounding fluid, and it can be decomposed into three principal axes of pitch and their associated moments of pitch. The moments of pitch predict the translational motion in a direction parallel to each pitch axis when the object is rotated around that axis and can be used to explain translational drift, particularly for rotating helices. We also provide a symmetrized boundary element model for blocks of the resistance tensor, allowing calculation of the pitch matrix for arbitrary rigid bodies. We analyze a range of chiral objects, including chiral molecules and helices. Chiral objects with a Cn symmetry axis with n > 2 show additional symmetries in their pitch matrices. We also show that some achiral objects have non-vanishing pitch matrices, and we use this result to explain recent observations of achiral microswimmers. We also discuss the small but non-zero pitch of Lord Kelvin's isotropic helicoid.
我们提出了一种关于螺距的理论,螺距是一种矩阵属性,与低雷诺数下刚体的旋转和平动耦合相关。螺距矩阵是与周围流体接触的物体的几何属性,它可分解为三个螺距主轴及其相关的螺距矩。当物体绕该轴旋转时,螺距矩可预测在平行于每个螺距轴方向上的平动,可用于解释平动漂移,特别是对于旋转螺旋。我们还为阻力张量块提供了一个对称化边界元模型,允许计算任意刚体的螺距矩阵。我们分析了一系列手性物体,包括手性分子和螺旋。具有n>2的Cn对称轴的手性物体在其螺距矩阵中表现出额外的对称性。我们还表明,一些非手性物体具有非零的螺距矩阵,并用这一结果解释了最近关于非手性微游动体的观察结果。我们还讨论了开尔文勋爵各向同性螺旋面的小但非零的螺距。