• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

一种以甲基丙烯酸苄酯为功能单体的具有简单聚合体系的吸油树脂。

An oil-absorbing resin with a simple polymerization system with benzyl methacrylate as a functional monomer.

作者信息

Zhou Yanjia, Zhang Ming, Liu Yongqiang, Xu Bo, Qiu Haiyan, Che Xiuli, Lan Guihong

机构信息

Department of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, People's Republic of China.

China Railway Water Group Co., Ltd., Xi'an 710100, People's Republic of China.

出版信息

R Soc Open Sci. 2023 Oct 11;10(10):230343. doi: 10.1098/rsos.230343. eCollection 2023 Oct.

DOI:10.1098/rsos.230343
PMID:37830033
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10565408/
Abstract

To solve the problem of the low absorbency of oil-absorbing resins, oil-absorbing resins (PAMs) were fabricated in this study by introducing commercially available benzyl methacrylate (BZMA) as a functional monomer copolymerized with stearyl methacrylate (SMA) and butyl acrylate (BA). The internal network structure of the PAMs expanded more easily when absorbing oils or organic solvents after introducing rigid groups of the benzene ring by an uncomplex polymerization process, which provided the oil-absorbing resin with good absorbency. The reagents were all commercially available, and there was no other pretreatment or posttreatment process. Then, the optimum parameters for the monomer feed ratio, water/oil mass ratio, and concentrations of initiator, stabilizer and crosslinker were studied. Simultaneously, the reusability, oil retention and thermal stability of PAMs were investigated in this article. The PAMs swelled in various oils and organic solvents (the values of oil absorbency were 44.52, 56.13, 25.54, 28.21, 32.85, 24.56, 14.17, 15.02 and 29.07 g g for CCl, CHCl, CHCl, benzene, toluene, xylene, n-hexane, 0# diesel oil and 93# gasoline, respectively) and displayed good oil absorbency, which met the absorption requirements for common oils or organic solvents.

摘要

为了解决吸油树脂吸油率低的问题，本研究通过引入市售甲基丙烯酸苄酯（BZMA）作为功能单体与甲基丙烯酸十八酯（SMA）和丙烯酸丁酯（BA）共聚来制备吸油树脂（PAMs）。通过非络合聚合过程引入苯环刚性基团后，PAMs的内部网络结构在吸收油或有机溶剂时更容易扩展，这使得吸油树脂具有良好的吸油率。所用试剂均为市售，且无需其他预处理或后处理过程。然后，研究了单体进料比、水/油质量比以及引发剂、稳定剂和交联剂浓度的最佳参数。同时，本文还研究了PAMs的可重复使用性、持油性和热稳定性。PAMs在各种油和有机溶剂中均能溶胀（对四氯化碳、三氯甲烷、二氯甲烷、苯、甲苯、二甲苯、正己烷、0#柴油和93#汽油的吸油值分别为44.52、56.13、25.54、28.21、32.85、24.56、14.17、15.02和29.07 g/g），并表现出良好的吸油率，满足对普通油或有机溶剂的吸收要求。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/4cb0de3a72bd/rsos230343f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/12c232a51319/rsos230343f01.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/aee76b018cba/rsos230343f02.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/a064ba8275ca/rsos230343f03.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/c7bc46eb8e1e/rsos230343f04.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/2cf33b1766ba/rsos230343f05.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/fe4c102ca7d3/rsos230343f06.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/1a9a479b4ef0/rsos230343f07.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/6dfc4cce36fb/rsos230343f08.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/53e7b59663c3/rsos230343f09.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/a3b189779b7f/rsos230343f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/dbaf1ad76b2e/rsos230343f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/409f15f2d69a/rsos230343f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/49dc9707e8d4/rsos230343f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/4cb0de3a72bd/rsos230343f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/12c232a51319/rsos230343f01.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/aee76b018cba/rsos230343f02.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/a064ba8275ca/rsos230343f03.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/c7bc46eb8e1e/rsos230343f04.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/2cf33b1766ba/rsos230343f05.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/fe4c102ca7d3/rsos230343f06.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/1a9a479b4ef0/rsos230343f07.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/6dfc4cce36fb/rsos230343f08.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/53e7b59663c3/rsos230343f09.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/a3b189779b7f/rsos230343f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/dbaf1ad76b2e/rsos230343f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/409f15f2d69a/rsos230343f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/49dc9707e8d4/rsos230343f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e9f/10565408/4cb0de3a72bd/rsos230343f14.jpg

相似文献

1
An oil-absorbing resin with a simple polymerization system with benzyl methacrylate as a functional monomer.一种以甲基丙烯酸苄酯为功能单体的具有简单聚合体系的吸油树脂。
R Soc Open Sci. 2023 Oct 11;10(10):230343. doi: 10.1098/rsos.230343. eCollection 2023 Oct.
2
β-Cyclodextrin-based oil-absorbent microspheres: preparation and high oil absorbency.基于β-环糊精的吸油微球：制备及高吸油性。
Carbohydr Polym. 2013 Jan 2;91(1):217-23. doi: 10.1016/j.carbpol.2012.08.036. Epub 2012 Aug 17.
3
Synthesis of the starch grafting of superabsorbent and high oil-absorbing resin.高吸水性与高吸油性树脂淀粉接枝的合成
J Environ Sci (China). 2013 Dec;25 Suppl 1:S97-S100. doi: 10.1016/S1001-0742(14)60635-5.
4
Preparation and oil absorbency of kapok-g-butyl methacrylate.木棉接枝甲基丙烯酸丁酯的制备及其吸油性
Environ Technol. 2018 May;39(9):1089-1095. doi: 10.1080/09593330.2017.1321689. Epub 2017 May 5.
5
Preparation of highly interconnected porous polymer microbeads suspension polymerization of high internal phase emulsions for fast removal of oil spillage from aqueous environments.高度互连的多孔聚合物微珠的制备 用于快速去除水环境中溢油的高内相乳液悬浮聚合
RSC Adv. 2019 Aug 15;9(44):25730-25738. doi: 10.1039/c9ra05220h. eCollection 2019 Aug 13.
6
Investigation on the Effect of Poly(butylmethacrylate)/attapulgite Nanocomposites for Oil Absorption.聚甲基丙烯酸丁酯/凹凸棒土纳米复合材料吸油性能的研究
Water Environ Res. 2016 Nov 1;88(11):1994-2000. doi: 10.2175/106143016X14609975747928.
7
Preparing an ATP/P (n-BuMA-St)/Fe O Oil-Absorbing Resin Composite via a Double Pickering Emulsion Template Method and Elucidation of Its Properties.通过双Pickering乳液模板法制备ATP/P(n - BuMA - St)/Fe₃O₄吸油树脂复合材料及其性能阐释
Chempluschem. 2022 Jul;87(7):e202200100. doi: 10.1002/cplu.202200100.
8
Organic-inorganic hybrid gels for the selective absorption of oils from water.用于从水中选择性吸收油类的有机-无机杂化凝胶。
Environ Sci Pollut Res Int. 2016 Jun;23(12):11695-707. doi: 10.1007/s11356-016-6342-9. Epub 2016 Mar 4.
9
Hydrophobic poly(alkoxysilane) organogels as sorbent material for oil spill cleanup.疏水性聚（烷氧基硅烷）有机凝胶作为溢油清理的吸附剂材料。
Mar Pollut Bull. 2015 Jul 15;96(1-2):155-64. doi: 10.1016/j.marpolbul.2015.05.033. Epub 2015 May 19.
10
Reusable organosilicon hybrid sorbents with tunable oil interest via PEG-PPG copolymer.可重复使用的有机硅混合吸附剂，通过 PEG-PPG 共聚物可调节油亲和力。
Chemosphere. 2021 Oct;281:130818. doi: 10.1016/j.chemosphere.2021.130818. Epub 2021 May 10.

引用本文的文献

1
Synthesis of a new oil-absorbing PVC oil boom and its application to maritime oil spills.新型吸油PVC围油栏的合成及其在海上溢油中的应用。
Sci Rep. 2024 Sep 2;14(1):20356. doi: 10.1038/s41598-024-71437-9.

本文引用的文献

1
β-Cyclodextrin-based oil-absorbent microspheres: preparation and high oil absorbency.基于β-环糊精的吸油微球：制备及高吸油性。
Carbohydr Polym. 2013 Jan 2;91(1):217-23. doi: 10.1016/j.carbpol.2012.08.036. Epub 2012 Aug 17.
2
Sorption of styrene from aqueous solutions with oil absorptive resin.用吸油树脂从水溶液中吸附苯乙烯。
J Environ Manage. 2009 Jan;90(1):217-21. doi: 10.1016/j.jenvman.2007.09.006. Epub 2007 Dec 21.