Wu Zhi, Liu Yifei, Zhou Jing, Zhao Hong, Qin Zhihui
School of Materials and Engineering, Hunan Institute of Technology, Hengyang 421002, China.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China.
Materials (Basel). 2023 Sep 22;16(19):6358. doi: 10.3390/ma16196358.
Multilayer films can achieve advanced properties and a wide range of applications. The heterogeneous interface plays an important role in the performances of multilayer films. In this paper, the effects of the interface of Ba(MgTa)O/PbZrTiO (BMT/PZT) thin films on dielectric behavior and temperature stability are investigated. The heterogeneous interface structures are characterized by Auger electron spectroscopy (AES). The PZT-BMT interface is different from the BMT-PZT interface in thickness. For the PZT-BMT interface, the PZT thin films are diffused to the whole BMT layers, and the interface thickness is about 90 nm, while the BMT-PZT interface's thickness is only about 8.6 nm. The presence of heterogeneous interfaces can improve the performances of BMT/PZT thin films and expand their applications. The dielectric constant of BBPP thin films is significantly lower than BPBP thin films, while the dielectric loss is exactly the opposite. The more interfaces there are, the greater the dielectric constant. The relationship between the electric-field-dependent dielectric constant curve and the P-E curve is established. The equivalent interface barrier of the diode is used to show that the dielectric peaks under the positive and negative voltage are different. Similarly, heterogeneous interfaces show a certain improvement in dielectric tunability and temperature stability.
多层膜可以实现先进的性能和广泛的应用。异质界面在多层膜的性能中起着重要作用。本文研究了Ba(MgTa)O/PbZrTiO(BMT/PZT)薄膜的界面对介电行为和温度稳定性的影响。采用俄歇电子能谱(AES)对异质界面结构进行了表征。PZT-BMT界面和BMT-PZT界面在厚度上有所不同。对于PZT-BMT界面,PZT薄膜扩散到整个BMT层,界面厚度约为90nm,而BMT-PZT界面的厚度仅约为8.6nm。异质界面 的存在可以提高BMT/PZT薄膜的性能并拓展其应用。BBPP薄膜的介电常数明显低于BPBP薄膜,而介电损耗情况则相反。界面越多,介电常数越大。建立了电场依赖介电常数曲线与P-E曲线之间的关系。利用二极管的等效界面势垒表明正、负电压下的介电峰不同。同样,异质界面在介电可调性和温度稳定性方面也有一定的改善。