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用于在可见光照射下光降解染料的双硫化物纳米片原位修饰在氧化锌/醋酸纤维素复合薄膜上

In Situ Decoration of BiS Nanosheets on Zinc Oxide/Cellulose Acetate Composite Films for Photodegradation of Dyes under Visible Light Irradiation.

作者信息

Dan Yixiao, Xu Jialiang, Jian Jian, Meng Lingxi, Deng Pei, Yan Jiaqi, Yuan Zhengqiu, Zhang Yusheng, Zhou Hu

机构信息

Hunan Engineering Research Center for Functional Film Materials, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China.

Furong College, Hunan University of Arts and Science, Changde 415000, China.

出版信息

Molecules. 2023 Sep 29;28(19):6882. doi: 10.3390/molecules28196882.

Abstract

A novel BiS-zinc oxide/cellulose acetate composite film was prepared through a blending-wet phase conversion and in situ precipitate method. The results revealed that the incorporation of BiS in the film increased the cavity density and uniformity, which provided additional space for the growth of active species and improved the interaction between dye pollutants and active sites. Zinc oxide acted as a mediator to facilitate the separation of electron-hole pairs effectively preventing their recombination, thus reducing the photo-corrosion of BiS. As a result, the BiS-ZnO/CA composite film exhibited favorable photocatalytic activity in the degradation of various dyes. Additionally, the composite film displayed effortless separation and recovery without the need for centrifugation or filtration, while maintaining its exceptional catalytic performance even after undergoing various processes.

摘要

通过共混-湿相转化和原位沉淀法制备了一种新型的BiS-氧化锌/醋酸纤维素复合膜。结果表明,BiS掺入膜中增加了空穴密度和均匀性,为活性物种的生长提供了额外空间,并改善了染料污染物与活性位点之间的相互作用。氧化锌作为一种媒介,有效地促进了电子-空穴对的分离,防止它们复合,从而减少了BiS的光腐蚀。结果,BiS-氧化锌/醋酸纤维素复合膜在各种染料的降解中表现出良好的光催化活性。此外,该复合膜无需离心或过滤即可轻松分离和回收,并且即使经过各种处理后仍能保持其优异的催化性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/73a8/10574506/9ed186bc1faf/molecules-28-06882-g001.jpg

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