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InGaN/GaN界面处(a+c)型失配位错的解离

The dissociation of (a+c) misfit dislocations at the InGaN/GaN interface.

作者信息

Smalc-Koziorowska J, Moneta J, Muzioł G, Chromiński W, Kernke R, Albrecht M, Schulz T, Belabbas I

机构信息

Institute of High Pressure Physics, Polish Academy of Sciences, Warsaw, Poland.

Faculty of Materials Science and Engineering, Warsaw University of Technology, Warsaw, Poland.

出版信息

J Microsc. 2024 Mar;293(3):146-152. doi: 10.1111/jmi.13234. Epub 2023 Oct 17.

DOI:10.1111/jmi.13234
PMID:37846455
Abstract

In hexagonal materials, (a+c) dislocations are typically observed to dissociate into partial dislocations. Edge (a+c) dislocations are introduced into (0001) nitride semiconductor layers by the process of plastic relaxation. As there is an increasing interest in obtaining relaxed InGaN buffer layers for the deposition of high In content structures, the study of the dissociation mechanism of misfit (a+c) dislocations laying at the InGaN/GaN interface is then crucial for understanding their nucleation and glide mechanisms. In the case of the presented plastically relaxed InGaN layers deposited on GaN substrates, we observe a trigonal network of (a+c) dislocations extending at the interface with a rotation of 3° from <1 00> directions. High-resolution microscopy studies show that these dislocations are dissociated into two Frank-Shockley 1/6<2 03> partial dislocations with the I BSF spreading between them. Atomistic simulations of a dissociated edge (a+c) dislocation revealed a 3/5-atom ring structure for the cores of both partial dislocations. The observed separation between two partial dislocations must result from the climb of at least one of the dislocations during the dissociation process, possibly induced by the mismatch stress in the InGaN layer.

摘要

在六方材料中,通常观察到(a + c)位错会分解为部分位错。通过塑性弛豫过程,刃型(a + c)位错被引入到(0001)氮化物半导体层中。由于人们对获得用于沉积高铟含量结构的弛豫铟镓氮缓冲层的兴趣日益浓厚,因此研究位于铟镓氮/氮化镓界面处的失配位错(a + c)的解离机制对于理解它们的形核和滑移机制至关重要。对于沉积在氮化镓衬底上的呈现塑性弛豫的铟镓氮层,我们观察到一个(a + c)位错的三角网络在界面处延伸,其方向相对于<1 00>方向旋转了3°。高分辨率显微镜研究表明,这些位错分解为两个弗兰克 - 肖克利1/6<2 03>部分位错,中间有中间带条纹衬度(I BSF)扩展。对解离的刃型(a + c)位错的原子模拟揭示了两个部分位错核心的3/5原子环结构。观察到的两个部分位错之间的间距必定是由于解离过程中至少一个位错的攀移造成的,这可能是由铟镓氮层中的失配应力引起的。

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