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无金属的 2-异氰基联苯基环化反应：菲啶骨架合成。

Metal-free 2-isocyanobiaryl-based cyclization reactions: phenanthridine framework synthesis.

机构信息

Endocrinology and Metabolism Research Center, Endocrinology and Metabolism Clinical Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran.

出版信息

Mol Divers. 2024 Feb;28(1):419-435. doi: 10.1007/s11030-023-10743-2. Epub 2023 Oct 17.

DOI:10.1007/s11030-023-10743-2
PMID:37847467
Abstract

The development of transition metal-free 2-isocyanobiaryl-based reactions has received much attention due to the widespread presence of phenanthidine frameworks as products in pharmacological chemistry and materials science. This review article focuses on the achievements from 2013 until now in various metal-free catalyzed reactions and discusses challenging mechanisms and features of the transformations.

摘要

由于菲啶骨架作为药理学和材料科学领域产物的广泛存在，无过渡金属的 2-异氰基联苯基反应的发展受到了广泛关注。本文综述了 2013 年至今各种无金属催化反应的成果，并讨论了转化的挑战性机制和特点。

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