Liu Qianqian, Zhou Zheng, Huang Zhibin, Zhao Yingsheng
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science Soochow University, Suzhou 215123, PR China.
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453000, P. R. China.
J Org Chem. 2023 Nov 3;88(21):15350-15357. doi: 10.1021/acs.joc.3c01843. Epub 2023 Oct 23.
A palladium-catalyzed oxidative amination of inactive olefins with an aromatic amine was developed using a copper acetate oxidant to yield corresponding secondary and tertiary enamines in moderate to good yields. This new procedure outlines an efficient approach for the construction of enamine skeletons.
利用醋酸铜氧化剂，开发了一种钯催化的惰性烯烃与芳香胺的氧化胺化反应，以中等至良好的产率生成相应的仲烯胺和叔烯胺。这一新方法概述了一种构建烯胺骨架的有效途径。
