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土壤中铅钝化剂的理化性质研究

Study on the physical and chemical properties of lead passivating agent in soil.

作者信息

Han Chengyu, Li Juan, Shen Jianglong

机构信息

School of Human Settlements and Civil Engineering, Xi'an Jiaotong University, Xi'an, 710049, China.

Shaanxi Engineering Research Center of Land Consolidation, Xi'an, 710075, China.

出版信息

Sci Rep. 2023 Oct 25;13(1):18213. doi: 10.1038/s41598-023-45567-5.

Abstract

With the rapid development of industry, heavy metal pollution has seriously damaged the health of soil, and heavy metals spread through the food chain, posing a threat to human health. The firm existence of heavy metals in soil under earthy conditions is a center trouble faced by soil dense metal pollution solidification and correction technology. However, the existing investigation results are mostly controlled to soil passivation experiments using various materials. Macroscopically, heavy metal passivation materials have been selected, but the intrinsic mechanisms of different compound functional groups in soil passivation have been ignored. With the common heavy metal ion Pb as an example, the stability of the combination of heavy metal ions and common ion groups in soil was analyzed in this study by using quantum chemical calculation as the theoretical guidance. The results show that SO and PO, as functional groups of passivating agents, are used to control lead pollution and have been verified to have good effects. When the pollution is particularly serious and not easy to passivation and precipitation, Fe can be considered to enhance the passivation effect.

摘要

随着工业的快速发展,重金属污染已严重损害土壤健康,且重金属通过食物链传播,对人类健康构成威胁。在实际条件下土壤中重金属的稳定存在是土壤重金属污染固化修复技术面临的核心难题。然而,现有研究结果大多局限于使用各种材料进行土壤钝化实验。从宏观上看,已筛选出重金属钝化材料,但土壤钝化中不同复合官能团的内在机制却被忽视。本研究以常见重金属离子铅为例,以量子化学计算为理论指导,分析了土壤中重金属离子与常见离子基团结合的稳定性。结果表明,作为钝化剂官能团的SO和PO用于控制铅污染,且已证实效果良好。当污染特别严重且不易钝化沉淀时,可考虑使用铁来增强钝化效果。

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