• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

钌簇嵌入的NiMoO(P)纳米片阵列作为用于风能/太阳能制氢系统的高效双功能催化剂

Ru Cluster Incorporated NiMoO(P) Nanosheet Arrays as High-Efficient Bifunctional Catalyst for Wind/Solar-To-Hydrogen Generation Systems.

作者信息

Wu Shengye, Chen Ding, Li Shang, Zeng Yuting, Wang Tao, Zhang Jian, Yu Jun, Mu Shichun, Tang Haolin

机构信息

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China.

Key Laboratory of Fuel Cell Technology of Hubei Province, Wuhan University of Technology, Wuhan, 430070, China.

出版信息

Adv Sci (Weinh). 2023 Dec;10(35):e2304179. doi: 10.1002/advs.202304179. Epub 2023 Oct 25.

DOI:10.1002/advs.202304179
PMID:37880875
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10724388/
Abstract

Developing cost-efficient bifunctional water splitting catalysts is crucial for sustainable hydrogen energy applications. Herein, ruthenium (Ru)-incorporated and phosphorus (P)-doped nickel molybdate (Ru-NiMoO(P) ) nanosheet array catalysts are synthesized. Due to the synergy of Ru clusters and NiMoO(P) by the modulated electronic structure and the rich active sites, impressively, Ru-NiMoO(P) exhibits superior OER (194 mV @ 50 mA cm ) and HER (24 mV @ 10 mA cm ) activity in alkaline media, far exceeding that of commercial Pt/C and RuO catalysts. Meanwhile, as bifunctional catalyst, to drive the overall water splitting at the current density of 10 mA cm , Ru-NiMoO(P) requires only 1.45 V and maintaining stable output for 100 h. Furthermore, Ru-NiMoO(P) also possesses excellent capability for seawater electrolysis hydrogen production. Moreover, the successful demonstration of wind and solar hydrogen production systems provide the feasibility of the ultra-low Ru loading catalyst for large-scale hydrogen production in the future.

摘要

开发具有成本效益的双功能水分解催化剂对于可持续氢能应用至关重要。在此，合成了掺钌（Ru）和磷（P）掺杂的钼酸镍（Ru-NiMoO(P)）纳米片阵列催化剂。由于Ru团簇与NiMoO(P)之间通过调制电子结构和丰富的活性位点产生协同作用，令人印象深刻的是，Ru-NiMoO(P)在碱性介质中表现出优异的析氧反应（在50 mA cm时为194 mV）和析氢反应（在10 mA cm时为24 mV）活性，远远超过商业Pt/C和RuO催化剂。同时，作为双功能催化剂，为了在10 mA cm的电流密度下驱动整体水分解，Ru-NiMoO(P)仅需要1.45 V，并能保持100小时的稳定输出。此外，Ru-NiMoO(P)还具有出色的海水电解制氢能力。此外，风能和太阳能制氢系统的成功示范为未来大规模制氢的超低Ru负载催化剂提供了可行性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/473812b07d90/ADVS-10-2304179-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/99bb490d3d19/ADVS-10-2304179-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/760a6a2c06b2/ADVS-10-2304179-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/8b5c9de012bd/ADVS-10-2304179-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/c0758833dfec/ADVS-10-2304179-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/2b4516a53d40/ADVS-10-2304179-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/473812b07d90/ADVS-10-2304179-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/99bb490d3d19/ADVS-10-2304179-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/760a6a2c06b2/ADVS-10-2304179-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/8b5c9de012bd/ADVS-10-2304179-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/c0758833dfec/ADVS-10-2304179-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/2b4516a53d40/ADVS-10-2304179-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc0/10724388/473812b07d90/ADVS-10-2304179-g003.jpg

相似文献

1
Ru Cluster Incorporated NiMoO(P) Nanosheet Arrays as High-Efficient Bifunctional Catalyst for Wind/Solar-To-Hydrogen Generation Systems.钌簇嵌入的NiMoO(P)纳米片阵列作为用于风能/太阳能制氢系统的高效双功能催化剂
Adv Sci (Weinh). 2023 Dec;10(35):e2304179. doi: 10.1002/advs.202304179. Epub 2023 Oct 25.
2
Ultralow Ru Incorporated Amorphous Cobalt-Based Oxides for High-Current-Density Overall Water Splitting in Alkaline and Seawater Media.用于碱性和海水介质中高电流密度全水分解的超低钌掺杂非晶态钴基氧化物
Small. 2021 Oct;17(39):e2102777. doi: 10.1002/smll.202102777. Epub 2021 Aug 12.
3
Crystalline Ru-Decorated MOF-Derived Amorphous CoMo-LDH Nanosheet Arrays as Bifunctional Catalysts for Overall Natural Seawater Electrolysis.晶体钌修饰的金属有机框架衍生非晶态钴钼层状双氢氧化物纳米片阵列作为用于全天然海水电解的双功能催化剂
ACS Appl Mater Interfaces. 2024 Oct 9;16(40):53675-53687. doi: 10.1021/acsami.4c09232. Epub 2024 Sep 24.
4
Ru-Incorporated Nickel Diselenide Nanosheet Arrays with Accelerated Adsorption Kinetics toward Overall Water Splitting.用于全解水且具有加速吸附动力学的钌掺杂二硒化镍纳米片阵列
Small. 2022 Feb;18(6):e2105305. doi: 10.1002/smll.202105305. Epub 2021 Dec 2.
5
Ruthenium/Ruthenium oxide hybrid nanoparticles anchored on hollow spherical Copper-Cobalt Nitride/Nitrogen doped carbon nanostructures to promote alkaline water splitting: Boosting catalytic performance via synergy between morphology engineering, electron transfer tuning and electronic behavior modulation.锚定在空心球形氮化铜钴/氮掺杂碳纳米结构上的钌/氧化钌杂化纳米颗粒用于促进碱性水分解：通过形貌工程、电子转移调控和电子行为调制之间的协同作用提高催化性能。
J Colloid Interface Sci. 2022 Nov 15;626:1070-1084. doi: 10.1016/j.jcis.2022.07.032. Epub 2022 Jul 8.
6
Heterostructured Inter-Doped Ruthenium-Cobalt Oxide Hollow Nanosheet Arrays for Highly Efficient Overall Water Splitting.用于高效全解水的异质结构间掺杂钌钴氧化物中空纳米片阵列
Angew Chem Int Ed Engl. 2020 Sep 21;59(39):17219-17224. doi: 10.1002/anie.202005436. Epub 2020 Jul 30.
7
Exceptional green hydrogen production performance of a ruthenium-modulated nickel selenide.钌调制硒化镍卓越的绿色制氢性能
Nanoscale. 2023 Dec 14;15(48):19604-19616. doi: 10.1039/d3nr04454h.
8
Thermal evaporation-driven fabrication of Ru/RuO nanoparticles onto nickel foam for efficient overall water splitting.通过热蒸发驱动在泡沫镍上制备钌/氧化钌纳米颗粒用于高效全解水
Nanoscale. 2024 Mar 28;16(13):6662-6668. doi: 10.1039/d3nr06204j.
9
Direct Electroplating Ruthenium Precursor on the Surface Oxidized Nickel Foam for Efficient and Stable Bifunctional Alkaline Water Electrolysis.在表面氧化泡沫镍上直接电镀钌前驱体用于高效稳定的双功能碱性水电解
Adv Mater. 2024 Aug;36(31):e2403151. doi: 10.1002/adma.202403151. Epub 2024 Jun 12.
10
Electronic Structure Engineering of Single-Atom Ru Sites via Co-N4 Sites for Bifunctional pH-Universal Water Splitting.通过Co-N4位点对单原子Ru位点进行电子结构工程用于双功能pH通用水分解
Adv Mater. 2022 May;34(21):e2110103. doi: 10.1002/adma.202110103. Epub 2022 Apr 24.

本文引用的文献

1
Dual-Atom Support Boosts Nickel-Catalyzed Urea Electrooxidation.双原子载体助力镍催化尿素电化学氧化。
Angew Chem Int Ed Engl. 2023 May 22;62(22):e202217449. doi: 10.1002/anie.202217449. Epub 2023 Apr 19.
2
Oxidation State Engineering in Octahedral Ni by Anchored Sulfate to Boost Intrinsic Oxygen Evolution Activity.通过锚定硫酸盐对八面体镍进行氧化态工程以提高本征析氧活性。
ACS Nano. 2023 Apr 11;17(7):6770-6780. doi: 10.1021/acsnano.2c12810. Epub 2023 Mar 20.
3
Supporting Trimetallic Metal-Organic Frameworks on S/N-Doped Carbon Macroporous Fibers for Highly Efficient Electrocatalytic Oxygen Evolution.
负载于 S/N 共掺杂碳大孔纤维上的三金属有机骨架用于高效电催化氧气析出。
Adv Mater. 2023 May;35(19):e2207888. doi: 10.1002/adma.202207888. Epub 2023 Mar 31.
4
Dynamic rhenium dopant boosts ruthenium oxide for durable oxygen evolution.动态铼掺杂促进氧化钌用于稳定的氧气析出反应。
Nat Commun. 2023 Jan 21;14(1):354. doi: 10.1038/s41467-023-35913-6.
5
Regulating the FeN Moiety by Constructing Fe-Mo Dual-Metal Atom Sites for Efficient Electrochemical Oxygen Reduction.通过构建铁-钼双金属原子位点调控FeN部分以实现高效电化学氧还原
Nano Lett. 2022 Dec 14;22(23):9507-9515. doi: 10.1021/acs.nanolett.2c03623. Epub 2022 Nov 15.
6
Selectively Coupling Ru Single Atoms to PtNi Concavities for High-Performance Methanol Oxidation via d-Band Center Regulation.通过d带中心调控将钌单原子选择性耦合到铂镍凹面用于高性能甲醇氧化
Angew Chem Int Ed Engl. 2022 Oct 17;61(42):e202207524. doi: 10.1002/anie.202207524. Epub 2022 Sep 14.
7
Ru-Co Pair Sites Catalyst Boosts the Energetics for the Oxygen Evolution Reaction.钌-钴双位点催化剂提高析氧反应的能量学性能。
Angew Chem Int Ed Engl. 2022 Aug 8;61(32):e202205946. doi: 10.1002/anie.202205946. Epub 2022 Jun 21.
8
Modulating Built-In Electric Field via Variable Oxygen Affinity for Robust Hydrogen Evolution Reaction in Neutral Media.通过可变氧亲和力调节内置电场以实现中性介质中稳健的析氢反应
Angew Chem Int Ed Engl. 2022 Mar 28;61(14):e202116057. doi: 10.1002/anie.202116057. Epub 2022 Feb 15.
9
Atomically Dispersed Co -N and Fe-N Costructures Boost Oxygen Reduction Reaction in Both Alkaline and Acidic Media.原子级分散的钴-氮和铁-氮共结构促进碱性和酸性介质中的氧还原反应。
Adv Mater. 2021 Dec;33(49):e2104718. doi: 10.1002/adma.202104718. Epub 2021 Oct 8.
10
Loading Single-Ni Atoms on Assembled Hollow N-Rich Carbon Plates for Efficient CO Electroreduction.将单镍原子负载在组装的富氮空心碳板上用于高效的CO电还原
Adv Mater. 2022 Jan;34(1):e2105204. doi: 10.1002/adma.202105204. Epub 2021 Oct 22.