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具有可调微波吸收性能的MXene/BN复合材料的制备

Preparation of MXene/BN Composites with Adjustable Microwave Absorption Performance.

作者信息

Zhang Weidong, Wen Haoliang, Gou Yaping, Zhao Yun, Zhang Zhiqiang, Qiao Yali

机构信息

College of Chemical Engineering, Qinghai University, Xining 810016, China.

State Key Laboratory of Plateau Ecology and Agriculture, Qinghai University, Xining 810016, China.

出版信息

Materials (Basel). 2023 Oct 18;16(20):6752. doi: 10.3390/ma16206752.

Abstract

The challenge of developing a high-efficiency microwave absorbent remains, because of the compatibility between microwave absorption and high-temperature-resistant performance in practical application. Herein, a facile method is used to obtain serial MXene/BN-zxy composites, where zx:y indicates the weight ratio of MXene and boron nitride (BN) in the composites, with adjustable microwave absorption performance (MAP) which can be regulated by the ratio of MXene and the BN nanosheet. In particular, the as-prepared absorbents with supercapacitance-like structure significantly enhanced the MAP and could be served more than 900 °C. The results of MAP reveal that the minimum reflection loss (RL) can reach -20.94 dB with a MXene/BN-101 composite coating thickness of 4.0 mm; the effective attenuation bandwidth (RL< -10 dB, i.e., 90% microwave energy is attenuated) is up to 9.71 GHz (7.94-17.65 GHz). From a detailed analysis, it is observed that attenuation is the critical limiting factor for MAPs rather than impedance mismatch, which can be assigned to the poor MAP of BN nanosheets. In any case, as-prepared absorbents have potential applications in the field of heating components.

摘要

由于在实际应用中微波吸收与耐高温性能之间的兼容性问题,开发高效微波吸收剂仍然面临挑战。在此,我们采用一种简便的方法制备了系列MXene/BN-zxy复合材料,其中zx:y表示复合材料中MXene与氮化硼(BN)的重量比,其微波吸收性能(MAP)可调,可通过MXene与BN纳米片的比例进行调节。特别地,所制备的具有类超级电容结构的吸收剂显著提高了MAP,并且能够在900℃以上使用。MAP结果表明,MXene/BN-101复合涂层厚度为4.0 mm时,最小反射损耗(RL)可达到-20.94 dB;有效衰减带宽(RL < -10 dB,即90%的微波能量被衰减)高达9.71 GHz(7.94 - 17.65 GHz)。通过详细分析发现,衰减是MAP的关键限制因素,而非阻抗失配,这可归因于BN纳米片较差的MAP。无论如何,所制备的吸收剂在加热部件领域具有潜在应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6355/10608534/14c348932bc3/materials-16-06752-g001.jpg

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