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荧光化学传感器的合成与应用:综述。

Synthesis and Applications of Fluorescent Chemosensors: A Review.

机构信息

Department of Chemistry, University of Malakand, Chakdara, Lower Dir, Pakistan, Khyber Pakhtunkhwa.

出版信息

J Fluoresc. 2024 Nov;34(6):2485-2494. doi: 10.1007/s10895-023-03455-1. Epub 2023 Oct 31.

DOI:10.1007/s10895-023-03455-1
PMID:37906359
Abstract

Fluorescent sensors have emerged as powerful tools in analytical chemistry for the detection and quantification of heavy and transition metal ions in aqueous samples. These metal ions pollute the environment and cause a number of diseases, such as irritability, anaemia, muscle paralysis, neurological damage, and memory loss. Moreover, we explore the wide spectrum of applications in environmental monitoring, where these sensors enable precise detection of contaminants, as well as in biomedical fields, facilitating diagnostic and therapeutic advancements. While highlighting the exceptional progress achieved in this field, I also address the challenges and future prospects for the continued development of fluorescent sensors, emphasizing their potential to shape the future of water quality assessment and analytical chemistry. Heavy and transition metals are of great concern because of their extreme toxicity even at very low concentration and tendency to be accumulated in bodies of living organisms. During the recent years, the design and synthesis of fluorescent chemosensors for sensing environmentally and biologically relevant important metals, particularly for heavy and transition metals, is of great interest. Opon complexation with heavy and transition metals, the fluorescence intensity of these fluorescent chemosensors either quenched or enhanced. The current review paper explains various fluorescent chemosensors for determination of toxic heavy and transition metals in environmental water samples.

摘要

荧光传感器已成为分析化学中用于检测和定量水样中重金属和过渡金属离子的有力工具。这些金属离子污染环境并导致许多疾病,如易怒、贫血、肌肉麻痹、神经损伤和记忆力丧失。此外,我们还探索了这些传感器在环境监测中的广泛应用,能够精确检测污染物,以及在生物医学领域,促进诊断和治疗的进步。在强调该领域取得的非凡进展的同时,我还讨论了荧光传感器持续发展所面临的挑战和未来前景,强调了它们在水质评估和分析化学未来发展中的潜力。重金属和过渡金属之所以受到极大关注,是因为它们即使在非常低的浓度下也具有极高的毒性,而且容易在生物体中积累。近年来,设计和合成用于感测环境和生物相关重要金属(特别是重金属和过渡金属)的荧光化学传感器引起了极大的兴趣。与重金属和过渡金属络合后,这些荧光化学传感器的荧光强度要么被猝灭,要么被增强。本综述文章解释了用于测定环境水样中有毒重金属和过渡金属的各种荧光化学传感器。

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